16200-57-0

Basic information

• Product Name: Toluene-4-sulfonic acid adamantan-1-yl ester
• Synonyms: Toluene-4-sulfonic acid adamantan-1-yl ester
• CAS NO: 16200-57-0
• Molecular Weight: 306.426
• Mol File: 16200-57-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Toluene-4-sulfonic acid adamantan-1-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Toluene-4-sulfonic acid adamantan-1-yl ester(16200-57-0)
• EPA Substance Registry System: Toluene-4-sulfonic acid adamantan-1-yl ester(16200-57-0)

Safety Data

• Hazardous Substances Data: 16200-57-0(Hazardous Substances Data)

Upstream product

• 768-95-6 1-adamanthanol 
• 98-59-9 p-toluenesulfonyl chloride 
• 19158-51-1 P-toluenesulfonyl cyanide 
• 876-53-9 1,3-dibromoadamantane 
• 768-90-1 1-Adamantyl bromide 
• 16836-95-6 silver(I) 4-methylbenzenesulfonate 
• 768-93-4 1-iodoadamantane 

Downstream Products

• 112543-88-1 1-Adamantan-1-yl-2,4,6-triphenyl-1,2,3,4-tetrahydro-[1,2,4,5]tetrazine 
• 85963-94-6 triphenylverdazylium p-toluenesulfonate 
• 38614-05-0 (3s,5s,7s)-1-phenoxyadamantane 
• 38614-06-1 2-((3r,5r,7r)-adamantan-1-yl)phenol 
• 79621-74-2 1-(4-phenoxybutoxy) adamantane 
• 935-56-8 1-chloroadamantane 
• 768-95-6 1-adamanthanol 
• 197569-70-3 N-1-adamantyl-N-p-tolylcarbamoyl chloride 
• 19984-39-5 (3s,5s,7s)-N-(p-tolyl)adamantan-1-amine 
• 57020-66-3 6-(4-nitro-phenyl)-2,4-diphenyl-1,2,3,4-tetrahydro-[1,2,4,5]tetrazine 
• 880-52-4 N-(1-adamantyl)acetamide 
• 17127-02-5 2,4-diphenyl-6-(4-methoxyphenyl)leucoverdazyl 
• 281-23-2 adamantane 
• 85963-93-5 2,4,6-triphenyl-1--1,2,3,4-tetrahydro-1,2,4,5-tetrazine 

Relevant articles and documents

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Solvent-free and selective tosylation of alcohols and phenols with p-toluenesulfonyl chloride by heteropolyacids as highly efficient catalysts

Tosylation of some alcohols and phenols has been directly carried out with p-toluenesulfonyl chloride using heterodoxy acids (H3PW 12O40, H3PMo12O40, A 3PW12O40, and AlPMo12O40) as catalysts in the absence of solvent. We found that heteropoly acids AlPW12O40 and AlPMo 12O40 were effective catalysts for the tosylation of alcohols and phenols. In the case of aliphatic alcohols, secondary alcohols undergo tosylation chemoselectively in the presence of primary hydroxyl groups. This new method consistently has the advantage of excellent yields and short reaction time.

Herstellung und Solvolyse von 3-substituierten p-Toluolsulfonsaeure-(1-adamantyl)estern

Methods for the preparation of some hitherto unknown 3-substituted 1-adamantyl toluenesulfonates are evaluated.Their solvolysis products in dioxane/water 70:30 are reported.