162239-52-3

Basic information

• Product Name: 7-Oxabicyclo[4.1.0]heptane, 1,5-dimethyl-
• Synonyms: 7-Oxabicyclo[4.1.0]heptane, 1,5-dimethyl-
• CAS NO: 162239-52-3
• Molecular Formula: C8H14O
• Molecular Weight: 126.2
• Mol File: 162239-52-3.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 152.5 °C
• Appearance: /
• Density: 0.905 g/cm3(Temp: 25 °C)
• CAS DataBase Reference: 7-Oxabicyclo[4.1.0]heptane, 1,5-dimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 7-Oxabicyclo[4.1.0]heptane, 1,5-dimethyl-(162239-52-3)
• EPA Substance Registry System: 7-Oxabicyclo[4.1.0]heptane, 1,5-dimethyl-(162239-52-3)

Safety Data

• Hazardous Substances Data: 162239-52-3(Hazardous Substances Data)

Upstream product

• 93-59-4 Perbenzoic acid 
• 2808-76-6 1,3-dimethylcyclohexene 

Relevant articles and documents

Diastereoselective epoxidation of cyclohexene derivatives by dioxiranes generated in situ. Importance of steric and field effects

In this paper, diastereoselective epoxidation of substituted cyclohexenes (substrates 1-7) by dioxiranes generated in situ from ketones and Oxone was systematically investigated. The results revealed that the diastereoselectivity was determined by the steric and field effects of both dioxiranes and substrates, and high diastereoselectivity can be achieved by tuning the ketone structure. Among the ketones tested, 12 and 19 gave the best diastereoselectivities.

Diastereoselectivity in the epoxidation of substituted cyclohexenes by dimethyldioxirane

Three series of compounds based on the cyclohexene framework have been epoxidized by dimetbyldioxirane. A pronounced dependence of epoxide diastereoselectivity on substituent has been observed. In addition there is a solvent influence on this stereoselectivity. The results have been explained by invoking steric, H-bonding, and dipole - dipole influences on the epoxide stereochemistry.