162271-31-0

Basic information

• Product Name: Methanone, (5-bromo-2-hydroxyphenyl)-2-pyridinyl-
• CAS NO: 162271-31-0
• Molecular Formula: C12H8BrNO2
• Molecular Weight: 278.105
• Mol File: 162271-31-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Methanone, (5-bromo-2-hydroxyphenyl)-2-pyridinyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Methanone, (5-bromo-2-hydroxyphenyl)-2-pyridinyl-(162271-31-0)
• EPA Substance Registry System: Methanone, (5-bromo-2-hydroxyphenyl)-2-pyridinyl-(162271-31-0)

Safety Data

• Hazardous Substances Data: 162271-31-0(Hazardous Substances Data)

Upstream product

• 1761-61-1 5-bromosalicyclaldehyde 
• 162270-32-8 5-bromo-2-hydroxy-α-(pyridin-2-yl)benzyl alcohol 
• 5813-64-9 2.2-dimethylpropylamine 
• 109-04-6 2-bromo-pyridine 
• 89-55-4 5-bromosalicyclic acid 

Downstream Products

• 1182372-38-8 4-bromo-2-[(isopropylimino)(pyridin-2-yl)methyl]phenol 
• 1182372-36-6 4-bromo-2-[(methylimino)(pyridin-2-yl)methyl]phenol 
• 1182372-33-3 4-bromo-2-[imino(pyridin-2-yl)methyl]phenol 
• 1563-56-0 2-amino-5-bromobenzoyl pyridine 

Relevant articles and documents

Photoinduced transition-metal- And external-photosensitizer-free intramolecular aryl rearrangementviaC(Ar)-O bond cleavage

The use of photochemical reactions that do not require expensive photocatalysts or transition metals is an environmentally friendly strategy for accomplishing a variety of structural transformations. Herein, we report a protocol for photoinduced transition-metal- and external-photocatalyst-free intramolecular heteroaryl/aryl rearrangement reactions of 2-heteroaryl/aryloxybenzaldehydes. The protocol was compatible with a variety of functionalities, including methyl, methoxy, cyano, ester, trifluoromethyl, halogen, and heteroaromatic rings. Control experiments suggested that the reaction proceededviaa photoinduced intramolecular heteroaryl/aryl rearrangement process involving photoexcitation of the aldehyde carbonyl group, radical addition, C-C bond formation and C(Ar)-O bond cleavage.

Pyridine derivatives, their production and use

Pyridine derivatives of the formula STR1 wherein the ring A stands for an optionally further substituted benzene ring; the ring B stands for an optionally substituted pyridine ring; Q stands for hydroxyl group, or OQ 1 or Q 1 wherein Q 1 stands for an optionally substituted aliphatic hydrocarbon group; and n denotes 0 or 1, or their salts, which have potassium.channel opening activity and are useful as therapeutic agents of circulatory diseases such as angina pectoris, hypertension, etc.