162507-72-4Relevant articles and documents
Catalytic production of oxygenated additives by glycerol etherification
Cannilla, Catia,Bonura, Giuseppe,Frusteri, Leone,Frusteri, Francesco
, p. 1248 - 1254 (2014)
In this work the etherification reaction of glycerol with isobutene (IB) and tert-butyl alcohol (TBA) has been studied with the aim of preparing mixtures with high content of poly-substituted ethers. The results obtained using solid acid catalysts have shown that the reaction with IB proceeds at a high rate but the formation of undesired di-isobutene (DIB) represents a serious problem when catalysts with high density of acid sites, such as Amberlyst, are used. When using TBA as a reactant, the main problem is the formation of water that, due to thermodynamic reasons, prevents the formation of poly-substituted ethers regardless of the catalyst used. Some preliminary experiments carried out with a water permselective tubular membrane have demonstrated that the yield of poly-substituted ethers significantly increases once water was selectively removed from the reaction medium by recirculation of the gas phase. [Figure not available: see fulltext.]
Nanostructured MFI-type zeolites as catalysts in glycerol etherification with tert-butyl alcohol
Simone, Nathália,Carvalho, Wagner A.,Mandelli, Dalmo,Ryoo, Ryong
, p. 115 - 121 (2016)
Hierarchical zeolite possessing MFI framework type was hydrothermally prepared using C22H45???N+(CH3)2???C6H12???N+(CH3)2???C6H13 as a structure-directing agent in a seed-assisted synthesis method. The nanosponge-like morphology was composed of a three-dimensional disordered network of MFI layers with 2.5?nm thickness supporting each other. Catalytic performance of the MFI nanosponge was investigated in glycerol etherification with tert-butyl alcohol in liquid phase and compared to conventional microporous MFI zeolite and MFI unilamelar nanosheet. The hierarchical zeolites were much more active, which can be attributed to the acid sites located on the external surfaces accessible for the reaction of bulky reactants.
Understanding the surface and structural characteristics of tungsten oxide supported on tin oxide catalysts for the conversion of glycerol
Srinivas,Raveendra,Parameswaram,Sai Prasad,Loridant,Lingaiah
, p. 897 - 908 (2015/08/04)
Abstract Catalysts with varying WO3 content on SnO2 were prepared and characterized by X-ray diffraction, in situ Raman spectroscopy, X-ray photoelectron spectroscopy and temperature programmed desorption of NH3. In situ Raman analysis reveals the presence isolated monomers and polymeric species of WO3. These catalysts were evaluated for the conversion of glycerol into value added chemicals. Etherification of glycerol with tertiary butanol and preparation of glycerol carbonate from glycerol and urea are studied over these catalysts. The catalytic activity results suggest that the glycerol conversion and selectivity depends on the morphology of WO3 which in turn is related to its content in the catalyst. The catalysts with 5 wt.% of WO3 on SnO2 resulted in high dispersion with larger number of strong acidic sites. The selectivity in the glycerol etherification is related to the nature of the catalyst and reaction time. These catalysts also exhibited high activity for synthesis of glycerol carbonate. The effect of various reaction parameters was studied to optimize the reaction conditions. The catalysts also exhibited consistent activity upon reuse.