162582-61-8

Basic information

• Product Name: (R)-2-(tert-Butyl-diphenyl-silanyloxy)-propionic acid isobutyl ester
• Synonyms: (R)-2-(tert-Butyl-diphenyl-silanyloxy)-propionic acid isobutyl ester
• CAS NO: 162582-61-8
• Molecular Weight: 384.591
• Mol File: 162582-61-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-2-(tert-Butyl-diphenyl-silanyloxy)-propionic acid isobutyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-2-(tert-Butyl-diphenyl-silanyloxy)-propionic acid isobutyl ester(162582-61-8)
• EPA Substance Registry System: (R)-2-(tert-Butyl-diphenyl-silanyloxy)-propionic acid isobutyl ester(162582-61-8)

Safety Data

• Hazardous Substances Data: 162582-61-8(Hazardous Substances Data)

Upstream product

• 61597-96-4 Isobutyl (R)-lactate 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 162680-08-2 (E)-(3S,6R)-6-(tert-Butyl-diphenyl-silanyloxy)-3-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-hept-4-enoic acid dimethylamide 
• 162680-09-3 (4S,5S)-4-[(E)-(R)-3-(tert-Butyl-diphenyl-silanyloxy)-but-1-enyl]-5-hydroxymethyl-dihydro-furan-2-one 
• 162582-65-2 (E)-(R)-4-(tert-Butyl-diphenyl-silanyloxy)-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-pent-1-en-3-one 
• 162582-63-0 dimethyl (3R)-3-((tert-butyl(diphenyl)silyl)oxy)-2-oxobutylphosphonate 

Relevant articles and documents

A 1,2-O-O-SILYL-MIGRATION-CLAISEN-REARRANGEMENT-SN2'-DISPLACEMENT SEQUENCE IN THE STEREOSELECTIVE SYNTHESIS OF 5-OXAPROSTANOID DERIVATIVES

A novel stereocontrolled route to 5-oxaprostaglandin and PGF intermediates is described, which starts from the ene-diols (6/7) and uses a sequence of Claisen rearrangement, 1,2-O-O-silyl migration and SN2'-cyclization reactions (9b10a/b via