162611-86-1Relevant articles and documents
Synthesis of [carbonyl-11C]acetophenone via the Stille cross-coupling reaction of [1-11C]acetyl chloride with tributylphenylstannane mediated by Pd2(dba)3/P(MeNCH2CH2)3N·HCl
Arai, Takuya,Kato, Koichi,Zhang, Ming-Rong
, p. 4788 - 4791 (2009)
The Stille cross-coupling reaction of [1-11C]acetyl chloride with tributylphenylstannane leading to [carbonyl-11C]acetophenone was studied with the goal of developing a new 11C-labeling method for positron emission tomography tracer synthesis. The coupled product [carbonyl-11C]acetophenone was synthesized using the Pd2(dba)3/P(MeNCH2CH2)3N·HCl system with a 60-61% radiochemical conversion from [1-11C]acetyl chloride (decay-corrected, n = 3).
Palladium-mediated 11C-carbonylative cross-coupling of alkyl/aryl iodides with organostannanes: An efficient synthesis of unsymmetrical alkyl/aryl [11C-carbonyl]ketones
Karimi, Farhad,Barletta, Julien,Langstroem, Bengt
, p. 2374 - 2378 (2005)
[11C]Carbon monoxide in low concentration, palladium complexes, alkyl/aryl iodides, and organostannanes are utilized in the synthesis of twenty alkyl [carbonyl-11C]ketones. The activated palladium(0) species [Pd{P(o-Tol)3}
Synthesis of alkyl/aryl [11C-carbonyl] aromatic ketones using [11C]carbon monoxide
Barletta, J.,Bjoerkman, M.,Oegren, M.,Laengstroem, B.
, p. S979 - S980 (2007/10/03)
-