16284-59-6

Basic information

• Product Name: trichlorochromium
• Synonyms: Chromic chloride Cr51
• CAS NO: 16284-59-6
• Molecular Formula: Cl3Cr
• Molecular Weight: 0
• Mol File: 16284-59-6.mol
• Article Data: 19

Chemical Properties

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Appearance: /
• Density: g/cm³
• CAS DataBase Reference: trichlorochromium(CAS DataBase Reference)
• NIST Chemistry Reference: trichlorochromium(16284-59-6)
• EPA Substance Registry System: trichlorochromium(16284-59-6)

Safety Data

• Hazardous Substances Data: 16284-59-6(Hazardous Substances Data)

Usage

Uses

Radioactive agent.

InChI:InChI=1/3ClH.Cr/h3*1H;/q;;;+3/p-3/i;;;1-1/rCl3Cr/c1-4(2)3/i4-1

Upstream product

• 75-44-5 phosgene 
• 10025-67-9 disulfur dichloride 
• 7782-50-5 chlorine 
• 56-23-5 tetrachloromethane 
• 10026-13-8 phosphorus pentachloride 
• 13820-25-2 hexamminechromium(III) chloride 
• 12018-22-3 chromium(II) sulfide 
• 7647-01-0 hydrogenchloride 
• 7440-47-3 chromium 
• 14977-61-8 chromyl chloride 
• 10025-87-3 trichlorophosphate 
• 10026-13-8 phosphorus pentachloride 
• 199620-14-9 chromium⁽⁰⁾ hexacarbonyl 

Downstream Products

• 121962-59-2 {P(1-adamantyl)B(2,4,6-Me₃C₆H₂)2}2 
• 12099-15-9 bis(η6-diphenyl)chromium(0) 
• 79725-75-0 {(1.3.5-(CH₃)3C₆H₃)2Cr}B(C₆H₅) 

Relevant articles and documents

Detuning the Honeycomb of the α-RuCl3 Kitaev Lattice: A Case of Cr3+ Dopant

Fine-tuning chemistry by doping with transition metals enables new perspectives for exploring Kitaev physics on a two-dimensional (2D) honeycomb lattice of α-RuCl3, which is promising in the field of quantum information protection and quantum computation. The key parameters to vary by doping are both Heisenberg and Kitaev components of the nearest-neighbor exchange interaction between the Jeff = 1/2 Ru3+ spins, depending strongly on the peculiarities of the crystal structure. Here, we present crystal growth by chemical vapor transport and structure elucidation of a solid solution series Ru1-xCrxCl3 (0 ≤ x ≤ 1), with Cr3+ ions coupled to the Ru3+ Kitaev host. The Cr3+ substitution preserves the honeycomb type lattice of α-RuCl3 and creates mixed occupancy of Ru/Cr sites without cationic order within the layers as confirmed by single-crystal X-ray diffraction and transmission electron microscopy investigations. In contrast to high-quality single crystals of α-RuCl3 with ABAB-stacked layers, the ternary compounds demonstrate a significant stacking disorder along the c-axis direction as evidenced by X-ray diffraction and high resolution scanning transmission electron microscopy (HR-STEM). Raman spectra of substituted samples are in line with the symmetry conservation of the parent lattice upon chromium doping. At the same time, our magnetic susceptibility data indicate that the Kitaev physics of α-RuCl3 is increasingly suppressed by the dominant spin-only driven magnetism of Cr3+ (S = 3/2) in Ru1-xCrxCl3.

Microwave-assisted carbohydrohalogenation of first-row transition-metal oxides (M = V, Cr, Mn, Fe, Co, Ni, Cu) with the formation of element halides

The anhydrous forms of first-row transition-metal chlorides and bromides ranging from vanadium to copper were synthesized in a one-step reaction using the relatively inexpensive element oxides, carbon sources, and halogen halides as starting materials. The reactions were carried out in a microwave oven to give quantitative yields within short reaction times.

An overview study of chlorination reactions applied to the primary extraction and recycling of metals and to the synthesis of new reagents

Energy intensive classical metallurgical processes, the depletion of high-grade ores and primary sources push the scientific and technical communities to treat lean and complex ores as well as secondary metal resources for the recovery of valuable metals.