16307-37-2

Basic information

• Product Name: bis(acetyloxy)(3-nitrophenyl)-lambda~3~-iodane
• CAS NO: 16307-37-2
• Molecular Formula: C₁₀H₁₀INO₆
• Molecular Weight: 367.094
• Mol File: 16307-37-2.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: bis(acetyloxy)(3-nitrophenyl)-lambda~3~-iodane(CAS DataBase Reference)
• NIST Chemistry Reference: bis(acetyloxy)(3-nitrophenyl)-lambda~3~-iodane(16307-37-2)
• EPA Substance Registry System: bis(acetyloxy)(3-nitrophenyl)-lambda~3~-iodane(16307-37-2)

Safety Data

• Hazardous Substances Data: 16307-37-2(Hazardous Substances Data)

Upstream product

• 645-00-1 m-iodonitrobenzene 
• 108-24-7 acetic anhydride 
• 64-19-7 acetic acid 
• 76-05-1 trifluoroacetic acid 
• 79-21-0 peracetic acid 

Downstream Products

• 64846-46-4 1-[bis(trifluoroacetoxy)iodo]-3-nitrobenzene 
• 99-65-0 meta-dinitrobenzene 
• 1396650-07-9 2-iodo-3-((3-nitrophenyl)(phenyl)amino)cyclohex-2-enone 
• 110441-18-4 (4-methoxyphenyl)(3'-nitrophenyl)iodonium tosylate 
• 1330786-73-6 (5-methyl-2-thienyl)(3-nitrophenyl)iodonium tosylate 
• 1330786-71-4 (3-nitrophenyl)(2-thienyl)iodonium tosylate 
• 1220515-97-8 3-[benzyl(3-nitrophenyl)amino]-2-iodocyclohex-2-enone 
• 1220515-90-1 2-iodo-3-[(3-nitrophenyl)(4-nitrophenyl)amino]cyclohex-2-enone 
• 1220515-93-4 3-[(2-chlorophenyl)(3-nitrophenyl)amino]-2-iodocyclohex-2-enone 
• 1155406-67-9 3-NO₂PhI(OCOCy)2 
• 90104-62-4 methyl 3-(acetyloxy)-3-phenylpropanoate 
• 1155406-21-5 methyl 3-acetoxy-3-(p-tolyl)propanoate 
• 1155406-17-9 methyl 3-acetoxy-3-(o-tolyl)propanoate 
• 1155406-19-1 methyl 3-acetoxy-3-(m-tolyl)propanoate 

Relevant articles and documents

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Oxidative Decarboxylation Enables Chemoselective, Racemization-Free Esterification: Coupling of α-Ketoacids and Alcohols Mediated by Hypervalent Iodine(III)

An α-ketoacid could be converted into a reactive acylating agent by treatment with hypervalent iodine(III) species, and in so doing, we discovered a novel decarboxylative acylation of alcohols that affords a variety of esters in excellent yields. The esterification has been applied to a sterol bearing a free carboxylic acid and shows unique chemoselectivity. The procedure is racemization-free and operates under mild conditions.

Safer Synthesis of (Diacetoxyiodo)arenes Using Sodium Hypochlorite Pentahydrate

A practical method for the preparation of (diacetoxyiodo)arene ArI(OAc)2 is described. The use of commercially available sodium hypochlorite pentahydrate (NaClO·5H2O) enabled safe, rapid, and inexpensive oxidation of iodoarenes with electron-withdrawing and -donating substituents. The method allows tandem divergent access to synthetically useful organo-λ3-iodanes such as hydroxyl(tosyloxy)iodobenzene, iodosylbenzene, iodonium ylide, etc.