16333-57-6

Basic information

• Product Name: 8-methyl-cis-bicyclo<4.3.0>nona-3,7-diene
• CAS NO: 16333-57-6
• Molecular Weight: 134.221
• Mol File: 16333-57-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 8-methyl-cis-bicyclo<4.3.0>nona-3,7-diene(CAS DataBase Reference)
• NIST Chemistry Reference: 8-methyl-cis-bicyclo<4.3.0>nona-3,7-diene(16333-57-6)
• EPA Substance Registry System: 8-methyl-cis-bicyclo<4.3.0>nona-3,7-diene(16333-57-6)

Safety Data

• Hazardous Substances Data: 16333-57-6(Hazardous Substances Data)

Upstream product

• 75-16-1 methylmagnesium bromide 
• 3048-65-5 cis-bicyclo<4.3.0>nona-3,7-diene 

Relevant articles and documents

TRANSANNULAR CYCLIZATION OF 3-METHYL-cis-BICYCLONONA-2,7-DIENE AND 3-METHYL- AND 3,4-DIMETHYL-cis-BICYCLONONA-3,7-DIENES. SYNTHESIS OF 5-SUBSTITUTED BREXANES

The reaction of formic acid and acetic acid with 3-methyl-cis-bicyclonona-2,7-diene, 3-methyl- and 3,4-dimethyl-cis-bicyclonona-3,7-dienes, and 3-methyl-cis-bicyclonon-7-en-3-ol leads to the exclusive formation of esters of 1-methyl- or 1,9-dimethyl-exo-brexan-5-ol with yields of 80-90percent.The reaction can be used as a convenient preparative method for the synthesis of 5-substituted brexanes.