1638142-45-6

Basic information

• Product Name: C₂₀H₂₂N₄*C₁₂H₁₂O₄^(2-)*Co⁽²⁺⁾
• CAS NO: 1638142-45-6
• Molecular Weight: 597.64
• Mol File: 1638142-45-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₀H₂₂N₄*C₁₂H₁₂O₄^(2-)*Co⁽²⁺⁾(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₀H₂₂N₄*C₁₂H₁₂O₄^(2-)*Co⁽²⁺⁾(1638142-45-6)
• EPA Substance Registry System: C₂₀H₂₂N₄*C₁₂H₁₂O₄^(2-)*Co⁽²⁺⁾(1638142-45-6)

Safety Data

• Hazardous Substances Data: 1638142-45-6(Hazardous Substances Data)

Upstream product

• 1059536-93-4 1,1′-(1,4-butanediyl)bis(2-methylbenzimidazole) 
• 2359-09-3 5-t-butylisophthalic acid 

Relevant articles and documents

Self-assembly of two 2D cobalt(II) coordination polymers constructed from 5-tert-butyl isophthalic acid and flexible bis(benzimidazole)-based ligands

Two cobalt(II) coordination polymers, [Co(L1)(tbi)(H2O)] n (1) and [Co(L2)(tbi)] n (2) (L1 = 1,4-bis(benzimidazole) butane, L2 = 1,4-bis(2-methylbenzimidazole)butane, H2tbi = 5-tert-butyl isophthalic acid) have been synthesized under hydrothermal conditions and characterized by physicochemical and spectroscopic methods as well as by single-crystal X-ray diffraction analysis. Both complexes exhibit similar 2D (4,4) layer structures, constructed from tbi2- and bis(benzimidazole)-based bridging ligands. The cobalt centers display different coordination environments, with an octahedral geometry in 1 and a distorted square-pyramidal configuration in 2. The thermal stabilities, fluorescence and catalytic properties of both complexes have been investigated.