16387-70-5Relevant articles and documents
A procedure for the oxidative 'dimerization' of aliphatic 1-alkynes
Brandsma,Verkruijsse,Walda
, p. 137 - 139 (1991)
Aliphatic 1-alkynes RC≡CH (R = alkyl) are readily converted into diynes RC≡CC≡CR, by introducing oxygen into a mixture of the acetylene and pyridine using copper(I)bromide as a catalyst and 1,8-diazabicyclo[5.4.0] undec-7-ene as a co-catalyst.
UTILIZATION OF "BIS(TRIPHENYLPHOSPHINE)PALLADIUM" AS CATALYST IN THE CROSS COUPLING REACTION OF TERMINAL ACETYLENES WITH ALKENYL HALIDES
Champs, F.,Chamorro, E.,Gasol, V.,Guerrero, A.
, p. 3211 - 3220 (2007/10/02)
Utilization of the 14-electron species "bis(triphenylphosphine)palladium (0)" as catalyst has been extended to the cross coupling reaction of a terminal acetylene with an alkenyl halide to prepare conjugated enynes, such as (Z)-11-hexadecen-13-ynyl acetate 1, which are direct precursors of Z,Z and Z,E dienyc unsaturated systems.