16395-67-8Relevant articles and documents
Experimental and theoretical studies on some energetic functionalized trimethylamine derivatives
Klapoetke, Thomas M.,Krumm, Burkhard,Scherr, Matthias,Xaver Steemann,Banert, Klaus,Joo, Young-Hyuk
, p. 11341 - 11345 (2009)
The synthesis and structural properties (from X-ray diffraction or B3LYP/6-31G(d) calculations) of three energetic compounds derived from tris(chloromethyl)amine and of tris(chloromethyl)amine itself were investigated and compared to those of compounds with similar structures. The compounds have almost planar NC3 units at their amine center, and the substituents bound to the CH2 groups tend to be reactive towards further substitution. Multiple hyperconjugation was used to explain these observations.
Synthesis of azidochloromethane and azidobromomethane
Banert, Klaus,Joo, Young-Hyuk,Rüffer, Tobias,Walfort, Bernhard,Lang, Heinrich
body text, p. 2880 - 2882 (2010/06/14)
By treatment of tris(azidomethyl)amine with dry hydrogen halide, azidochloromethane and azidobromomethane were prepared. The former product, which is more stable than the latter, was isolated as a colorless liquid. The desired azidohalomethanes are intermediates in the nucleophilic substitution of dihalomethanes to generate diazidomethane but could not be detected in this transformation.