164356-70-1

Basic information

• Product Name: [CpFe(CO)(CN(CH₂)3PPh₂)]I
• CAS NO: 164356-70-1
• Molecular Weight: 529.14
• Mol File: 164356-70-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: [CpFe(CO)(CN(CH₂)3PPh₂)]I(CAS DataBase Reference)
• NIST Chemistry Reference: [CpFe(CO)(CN(CH₂)3PPh₂)]I(164356-70-1)
• EPA Substance Registry System: [CpFe(CO)(CN(CH₂)3PPh₂)]I(164356-70-1)

Safety Data

• Hazardous Substances Data: 164356-70-1(Hazardous Substances Data)

Upstream product

• 12078-28-3 dicarbonylcyclopentadienyliodoiron(II) 
• 164356-59-6 N-(3-(diphenylphosphino)propyl)triphenylphosphinimine 

Downstream Products

• 1191887-88-3 [(C₅H₅)Fe(CO)((C₆H₅)2PC₃H₆NCP(C₆H₅)2)] 
• 1255141-89-9 [CpFe(CO)(C(OEt)N(CH₂)3PPh₂)] 
• 1255141-88-8 [CpFe(CO)(C(OMe)N(CH₂)3PPh₂)] 
• 1191887-89-4 [CpFe(CO)(C(SiPh₃)N(CH₂)3PPh₂)] 
• 1255141-90-2 [CpFe(CO)(C(OiPr)N(CH₂)3PPh₂)] 
• 164356-65-4 (C₅H₅)Fe(CO)((C₆H₅)2P(CH₂)3NHC(NHC₃H₇))⁽¹⁺⁾*I^(1-)=[(C₅H₅)Fe(CO)((C₆H₅)2P(CH₂)3NHC(NHC₃H₇))]I 
• 164356-78-9 (C₅H₅)Fe(CO)((C₆H₅)2P(CH₂)3NC)⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)Fe(CO)((C₆H₅)2P(CH₂)3NC)]PF₆ 

Relevant articles and documents

Phosphine-tethered carbene ligands: Template synthesis and reactivity of cyclic and acyclic functionalized carbenes

Reaction of the phosphine-tethered isocyanide iron(II) complex 1, [CpFe(CO)(PCN)]I, with primary and secondary amines forms the corresponding acyclic (diamino)carbene complexes [CpFe(CO)(PCXNH)]I; X = n-butylamine (4), 4-methylaniline (5), dihexylamine (6

Synthesis and coordination chemistry of a novel phosphinimine phosphine

The incorporation of a phosphinimino moiety into phosphine ligands to form a new bidentate PH3P=N(CH2)3PPh2 (1) is reported. Compound 1 can act as a σ-N and σ-P donor ligand or react with metal carbonyls to form isocyanide complexes. Complexes of (CO)4M-(1-P,N) [M = Mo (2), W (3)] were prepared from the reaction of Et4N[M(CO)5Br] with 1 in refluxing THF solution, whereas the isocyanide complexes of (CO)5MCN(CH2)3PPh2 [M = Cr (4), Mo (5), W (6)] are obtained from the reaction of M(CO)6 with 1 at 25°C. The deoxygenation nature is also shown in the reaction of CpFe(CO)2I, CpRu(CO)2I, Re(CO)5Br, and Re2(CO)10 with 1 to form the corresponding isocyanide complexes [CpFe(CO){CN(CH2)3-PPh2-C,P}]I (7), CpRu(CO)I{CN(CH2)3PPh2-C} (10), BrRe(CO)5-n{CN(CH2)3PPh2-C} n [n = 1 (12), 2 (14)], and Re2(CO)9{CN(CH2)3PPh2-C} (15), respectively. The free phosphine of 10 underwent exchange with one triphenylphosphine ligand in CpRu(PPh3)2Cl to yield the binuclear species [CpRu(PPh3)Cl{P(Ph2)(CH2) 3NC}Ru(CO)CpI] (11), whereas intramolecular ligand substitution occurred in both 12 and 15 to give Br(CO)3Re{CN(CH2)3PPh2-C,P} (13) and {μ-CN(CH2)3PPh2}Re2(CO) 8 (16). Reaction of (COD)PdCl2 with 1 produced the complex (1-P,N)PdCl2 (18), in which 1 acts as a σ-N, σ-P bidentate ligand. X-ray crystal structural analysis of [CpFe(CO){CN(CH2)3PPh2-C,P}]PF6 (7a) and 18 confirmed the formulation of both complexes. The C≡N bond distance [1.20(3) A?] of 7a is greater than those in the related iron-isocyanide complexes; the angle C-N-C [141(2)°] deviates from 180°, indicating that the resonance contribution of Fe=C=N- is more important than that of Fe-C≡N-. These observations are consistent with spectral data, the smaller infrared stretching wavenumber (2089 cm-1), and the greater shift (13C NMR δ 183.7 ppm) of the isocyanide moiety of 7.