1643565-84-7

Basic information

• Product Name: diethyl 2-((1S,2R)-1-methyl-4-oxo-1,2,3,4-tetrahydro-[1,1'-biphenyl]-2-yl)malonate
• Synonyms: diethyl 2-((1S,2R)-1-methyl-4-oxo-1,2,3,4-tetrahydro-[1,1'-biphenyl]-2-yl)malonate
• CAS NO: 1643565-84-7
• Molecular Weight: 344.408
• Mol File: 1643565-84-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: diethyl 2-((1S,2R)-1-methyl-4-oxo-1,2,3,4-tetrahydro-[1,1'-biphenyl]-2-yl)malonate(CAS DataBase Reference)
• NIST Chemistry Reference: diethyl 2-((1S,2R)-1-methyl-4-oxo-1,2,3,4-tetrahydro-[1,1'-biphenyl]-2-yl)malonate(1643565-84-7)
• EPA Substance Registry System: diethyl 2-((1S,2R)-1-methyl-4-oxo-1,2,3,4-tetrahydro-[1,1'-biphenyl]-2-yl)malonate(1643565-84-7)

Safety Data

• Hazardous Substances Data: 1643565-84-7(Hazardous Substances Data)

Upstream product

• 28937-18-0 4-methyl-4-phenyl-cyclohex-2,5-dien-1-one 
• 105-53-3 diethyl malonate 
• 17429-36-6 4-methyl-4-phenylcyclohex-2-enone 

Downstream Products

• 1643566-16-8 diethyl 2-((1R,2S)-2-methyl-5-oxo-2-phenylcyclohexyl)malonate 

Relevant articles and documents

Asymmetric organocatalytic desymmetrization of 4,4-disubstituted cyclohexadienones at high pressure: A new powerful strategy for the synthesis of highly congested chiral cyclohexenones

A highly diastereoselective and enantioselective method for the asymmetric desymmetrization of 4,4-disubstituted cyclohexadienones using the Michael addition reaction of malonates under catalysis with the primary amine-thiourea conjugate catalyst and PPY at high pressure was developed. This journal is the Partner Organisations 2014.