1646595-32-5

Basic information

• Product Name: 5'-(4-carboxyphenyl)-2'-(prop-2-yn-1-yloxy)-[1,1':3',1''-terphenyl]-4,4''-dicarboxylic acid
• CAS NO: 1646595-32-5
• Molecular Weight: 492.485
• Mol File: 1646595-32-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5'-(4-carboxyphenyl)-2'-(prop-2-yn-1-yloxy)-[1,1':3',1''-terphenyl]-4,4''-dicarboxylic acid(CAS DataBase Reference)
• NIST Chemistry Reference: 5'-(4-carboxyphenyl)-2'-(prop-2-yn-1-yloxy)-[1,1':3',1''-terphenyl]-4,4''-dicarboxylic acid(1646595-32-5)
• EPA Substance Registry System: 5'-(4-carboxyphenyl)-2'-(prop-2-yn-1-yloxy)-[1,1':3',1''-terphenyl]-4,4''-dicarboxylic acid(1646595-32-5)

Safety Data

• Hazardous Substances Data: 1646595-32-5(Hazardous Substances Data)

Usage

Structure

Terphenyl backbone with two carboxylic acid functional groups and a prop-2-yn-1-yloxy side chain attached to one of the phenyl rings

Functional groups

Two carboxylic acid groups, prop-2-yn-1-yloxy side chain

Family

Dicarboxylic acids

Components

Aromatic and aliphatic components

Potential applications

Materials science, organic chemistry, pharmaceutical research

Upstream product

• 118-79-6 2,4,6-tribromophenol 
• 1353118-72-5 dimethyl 2'-hydroxy-5'-(4-(methoxycarbonyl)phenyl)-[1,1':3',1''-terphenyl]-4,4''-dicarboxylate 
• 99768-12-4 4-methoxycarbonylphenylboronic acid 

Relevant articles and documents

Structure-assisted functional anchor implantation in robust metal-organic frameworks with ultralarge pores

A facile functionalization assisted by the structural attributes of PCN-333 has been studied while maintaining the integrity of the parent MOF including ultralarge pores, chemical robustness, and crystallinity. Herein we thoroughly analyzed ligand exchange phenomena in PCN-333 and demonstrate that the extent of exchange can be tailored by varying the exchange conditions as potential applications may require. Through this method a variety of functional groups are incorporated into PCN-333. To further show the capabilities of this system introduction of a BODIPY fluorophore as a secondary functionality was performed to the functionalized framework via a click reaction. We anticipate the PCN-333 with functional anchor can serve as a stable platform for further chemistry to be explored in future applications.