165261-51-8

Basic information

• Product Name: 9-bromo-N-(2,5-di-tert-butylphenyl)-perylene-3,4-dicarboxylic imide
• Synonyms: 9-bromo-N-(2,5-di-tert-butylphenyl)-perylene-3,4-dicarboxylic imide
• CAS NO: 165261-51-8
• Molecular Weight: 588.544
• Mol File: 165261-51-8.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 9-bromo-N-(2,5-di-tert-butylphenyl)-perylene-3,4-dicarboxylic imide(CAS DataBase Reference)
• NIST Chemistry Reference: 9-bromo-N-(2,5-di-tert-butylphenyl)-perylene-3,4-dicarboxylic imide(165261-51-8)
• EPA Substance Registry System: 9-bromo-N-(2,5-di-tert-butylphenyl)-perylene-3,4-dicarboxylic imide(165261-51-8)

Safety Data

• Hazardous Substances Data: 165261-51-8(Hazardous Substances Data)

Upstream product

• 21860-03-7 2,5-di-tert-butylaniline 
• 128-69-8 perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride 
• 117364-74-6 perylene-3,4-dicarboxylicacid anhydride 

Downstream Products

• 303089-30-7 9-(trimethylsilylethynyl)-N-(2,5-di-tert-butylphenyl)-perylene-3,4-dicarboxylic imide 
• 1352541-93-5 9-(N,N-bis(1H,1H,2H,2H-perfluorooctyl)amino)-N-(2,5-di-tert-butylphenyl)perylene-3,4-dicarboximide 
• 1422351-54-9 C₅₀H₄₀N₂O₂ 
• 1617508-00-5 C₃₇H₃₀N₂O₂ 
• 1617508-07-2 C₄₂H₃₀N₂O₇W 
• 1617508-06-1 C₄₂H₃₀MoN₂O₇ 
• 1617508-01-6 C₄₃H₃₀AuF₅N₂O₂ 
• 1617508-02-7 C₃₁H₂₀AuF₄NO 
• 1617508-05-0 C₄₂H₃₀CrN₂O₇ 
• 1617507-98-8 C₄₉H₄₀N₂O₂ 
• 1250889-93-0 PtBr(C₂₂H₉O₂NC₆H₃(C(CH₃)3)2)(P(C₂H₅)3)2 

Relevant articles and documents

Long-lived triplet excited state in a platinum(ii) perylene monoimide complex

We report the synthesis and solution based photophysical properties of a new Pt(ii)-terpyridine complex coupled to a perylene monoimide (PMI) chromophoric unit through an acetylene linkage. This structural arrangement resulted in quantitative quenching of the highly fluorescent PMI chromophore by introducing metal character into the lowest energy singlet state, thereby leading to the formation of a long-lived PMI-ligand localized triplet excited state (τ = 8.4 μs). Even though the phosphorescence from this triplet state was not observed, highly efficient quenching of this excited state by dissolved oxygen and the observation of singlet oxygen photoluminescence in the near-IR at 1270 nm initially pointed towards triplet excited state character. Additionally, the coincidence of the excited state absorbance difference spectra from the sensitized PMI ligand using a triplet donor and the Pt-PMI complex provided strong evidence for this triplet state assignment, which was further supported by TD-DFT calculations.

Stokes shift/emission efficiency trade-off in donor-acceptor perylenemonoimides for luminescent solar concentrators

Perylenediimides (PDIs) are among the best performing organic luminescent materials, both in terms of emission efficiency and chemical and photochemical stability because of their rigid, symmetric and planar structure; however, they exhibit very small Sto

Supercritical carbon dioxide as a solvent for deposition of a tailored dye in dye sensitized solar cells

We report a new technique whereby dyes can be deposited onto metal oxide surfaces using supercritical carbon dioxide (scCO2) for use in solar cell applications. This process eliminates the need for hazardous organic solvents and waste solvents generated during the dyeing process. The solubility of a perylene anhydride dye in scCO2 is enhanced by the incorporation of fluorinated alkyl subsituents and the use of masked carboxylic binding groups. This allows fast deposition of the dye onto the TiO2 photoanode, resulting in efficient photovoltaic performance. The unreacted dye is then easily recovered in a solid form after the deposition process by venting the carbon dioxide.