16538-47-9

Basic information

• Product Name: (1Z)-1-Iodo-1-hexene
• Synonyms: (1Z)-1-Iodo-1-hexene;(Z)-1-Iodo-1-hexene
• CAS NO: 16538-47-9
• Molecular Formula: C₆H₁₁I
• Molecular Weight: 210.06
• Mol File: 16538-47-9.mol
• Article Data: 21

Chemical Properties

• Boiling Point: 151.64°C (estimate)
• Appearance: /
• Density: 1.4517 (rough estimate)
• Refractive Index: 1.4970 (estimate)
• CAS DataBase Reference: (1Z)-1-Iodo-1-hexene(CAS DataBase Reference)
• NIST Chemistry Reference: (1Z)-1-Iodo-1-hexene(16538-47-9)
• EPA Substance Registry System: (1Z)-1-Iodo-1-hexene(16538-47-9)

Safety Data

• Hazardous Substances Data: 16538-47-9(Hazardous Substances Data)

Upstream product

• 590-27-2 (E)-1,2-diiodoethene 
• 693-02-7 hex-1-yne 
• 109-65-9 1-bromo-butane 
• 74-86-2 acetylene 
• 66225-50-1 di-iodohexane 
• 76346-98-0 (Z)-(1-iodo-1-hexenyl)trimethylsilane 
• 75-11-6 diiodomethane 
• 34009-04-6 phenyl pentyl sulfone 
• 1119-64-8 1-bromohexyne 
• 109-72-8 n-butyllithium 
• 693-03-8 n-butyl magnesium bromide 
• 1119-67-1 1-iodo-1-hexyne 
• 54731-58-7 (E)-1-trimethylsilyl-1-hexene 
• 52835-06-0 (Z)-hex-1-enyl(trimethyl)silane 

Downstream Products

• 1370406-97-5 C₁₅H₂₂O 
• 1352034-77-5 (Z)-1-((tert-butyldiphenylsilyl)oxy)dec-5-en-4-ol 
• 54354-55-1 (Z)-1-Hexen-1-boronsaeure 
• 1374870-92-4 (2R,4S,5R)-4-[(R,2Z,4Z)-1-hydroxy-3-(tert-butyldimethylsilyl)nona-2,4-dienyl]-2-phenyl-1,3-dioxan-5-ol 
• 1273587-37-3 (2Z,5Z)-4-methyl-2-phenyldeca-2,5-dienenitrile 
• 1273587-35-1 (Z)-3-(hex-1-en-1-yl)cyclohex-1-enecarbonitrile 
• 30651-68-4 (5E,7E)-5,7-dodecadiene 
• 21293-04-9 (5E,7Z)-5,7-dodecadiene 
• 6108-62-9 (5Z,7Z)-5,7-dodecadiene 
• 1113018-89-5 (1Z,5Z)-1-phenyl-2-(trimethylsilyl)deca-1,5-dien-3-yne 
• 15325-54-9 (Z)-hex-1-en-1-ylbenzene 

Relevant articles and documents

Convenient Procedure for the Synthesis of (E)-1-Bromo-1-alkenes and (Z)-1-Iodo-1-alkenes

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Preparation and synthetic transformation of alkenyl carbamates into vinyl zirconocene derivatives

The carbocupration reaction of alkynyl carbamates leads to the stereospecific preparation of polysubstituted alkenyl carbamates. Subsequent treatment of these enol carbamates with the Negishi reagent gave the corresponding vinyl zirconocene species. Georg Thieme Verlag Stuttgart.

First total synthesis of Debilisone C

Total synthesis of Debilisone C, a lactone containing conjugated endiyne has been achieved. The adopted strategy involves the stereoselective construction of the five membered lactone ring and the C20 endiyne chain followed by regioselective coupling of both the parts. The lactone was obtained from the oxidative cleavage of the hydroxy olefin which was derived from the benzyl protected S-epichlorohydrine by regioselective epoxide opening with allyl trimethyl silane in presence of a Lewis acid at -78 °C. Takai olefination, Pd0/Ag1 catalyzed cross-coupling reaction and selective substitution of trimethylsilyl groups were successfully utilized to establish the C20 polyyne chain. The final coupling of both the parts have been carried out by alkyl coupling using LDA in THF-DMPU (1 : 1).

One-pot synthesis of telluroketene acetals and haloketene acetals using sp2 geminated hetero organobismetallic intermediates

A novel one-pot synthesis of 1,1-dihalo-1-alkenes and 1,1-bis(butyltelluro) -1-alkenes was developed from hydrozirconation of alkynylzinc bromide with Cp2Zr(H)Cl and subsequent capture of the Zn/Zr 1,1-heterodimetallo-1- alkene intermediates wi