165817-38-9

Basic information

• Product Name: methoxymethoxyacetic acid (1R)-1-[(1R,5S)-5-benzyloxy-1-(4-methoxybenzyloxy)hexyl]allyl ester
• Synonyms: methoxymethoxyacetic acid (1R)-1-[(1R,5S)-5-benzyloxy-1-(4-methoxybenzyloxy)hexyl]allyl ester
• CAS NO: 165817-38-9
• Molecular Weight: 486.606
• Mol File: 165817-38-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methoxymethoxyacetic acid (1R)-1-[(1R,5S)-5-benzyloxy-1-(4-methoxybenzyloxy)hexyl]allyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: methoxymethoxyacetic acid (1R)-1-[(1R,5S)-5-benzyloxy-1-(4-methoxybenzyloxy)hexyl]allyl ester(165817-38-9)
• EPA Substance Registry System: methoxymethoxyacetic acid (1R)-1-[(1R,5S)-5-benzyloxy-1-(4-methoxybenzyloxy)hexyl]allyl ester(165817-38-9)

Safety Data

• Hazardous Substances Data: 165817-38-9(Hazardous Substances Data)

Upstream product

• 165817-36-7 (2R,4E,6S)-6-benzyloxy-2-(4-methoxybenzyloxy)hept-4-enoic acid methyl ester 
• 403694-63-3 (2R,6S)-6-benzyloxy-2-(4-methoxybenzyloxy)heptanoic acid methyl ester 
• 132974-57-3 O-(methoxymethyl)glycolic acid 
• 165817-37-8 (3R,4R,8S)-8-benzyloxy-4-(4-methoxybenzyloxy)non-1-en-3-ol 

Downstream Products

• 20350-15-6 (+)-brefeldin A 
• 165817-40-3 (2S,4E,6R,10S)-10-benzyloxy-6-hydroxy-2-methoxymethoxyundec-4-enoic acid methyl ester 
• 165817-34-5 (1R,2S,4S)-2-[(1E,6S)-6-benzyloxyhept-1-enyl]-4-methoxymethoxycyclopentanecarboxylic acid ethyl ester 
• 403694-62-2 (3R,4E,9S)-9-benzyloxy-3-[(2S)-3-iodo-2-methoxymethoxypropyl]dec-4-enoic acid ethyl ester 
• 165817-42-5 (3R,4E,9S)-9-benzyloxy-3-[(2S)-3-hydroxy-2-methoxymethoxypropyl]dec-4-enoic acid ethyl ester 
• 165817-41-4 (2S,4R)-4-[(6S)-6-benzyloxyhept-1-enyl]-2-methoxymethoxyhexanedioic acid 6-ethyl ester 1-methyl ester 
• 165817-39-0 (2S,4E,6R,10S)-10-benzyloxy-6-(4-methoxybenzyloxy)-2-methoxymethoxyundec-4-enoic acid methyl ester 

Relevant articles and documents

Asymmetric total synthesis of (+)-brefeldin A from (S)-lactate by triple chirality transfer process and nitrile oxide cycloaddition

A novel synthesis of (+)-brefeldin A (1) has been accomplished on the basis of triple chirality transfer methodology, intramolecular ester enolate alkylation, and both intra- and intermolecular nitrile oxide cycloaddition strategies.