16584-01-3

Basic information

• Product Name: 2-butyl-2H-benzo[d][1,2,3]triazole
• Synonyms: 2-butyl-2H-benzo[d][1,2,3]triazole;2-Butyl-2H-benzotriazole;2-Butylbenzotriazole;2-butyl-2H-benzo[d][1,2,3]triazole（WS203414）
• CAS NO: 16584-01-3
• Molecular Formula: C₁₀H₁₃N₃
• Molecular Weight: 175
• EINECS: -0
• Mol File: 16584-01-3.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 292℃
• Flash Point: 130℃
• Appearance: /
• Density: 1.12
• CAS DataBase Reference: 2-butyl-2H-benzo[d][1,2,3]triazole(CAS DataBase Reference)
• NIST Chemistry Reference: 2-butyl-2H-benzo[d][1,2,3]triazole(16584-01-3)
• EPA Substance Registry System: 2-butyl-2H-benzo[d][1,2,3]triazole(16584-01-3)

Safety Data

• Hazardous Substances Data: 16584-01-3(Hazardous Substances Data)

Upstream product

• 95-14-7 1,2,3-Benzotriazole 
• 591-50-4 iodobenzene 
• 429-41-4 tetrabutyl ammonium fluoride 

Downstream Products

• 14850-23-8 trans-4-Octene 
• 7642-15-1 (Z)-oct-4-ene 

Relevant articles and documents

N-arylations of nitrogen-containing heterocycles with aryl and heteroaryl halides using a copper(I) oxide nanoparticle/1,10-phenanthroline catalytic system

A general procedure for solvent-free N-arylations of nitrogen-containing heterocycles, i.e. imidazoles, triazoles, and indoles, with aryl and heteroaryl halides catalyzed by copper(I) oxide (Cu2O) nanoparticles is demonstrated. Four types of Cu2O were evaluated: the bulky compound and its cubic, octahedral, and spherical nanoparticulate forms. The results show that Cu2O nanoparticles, in particular the cubic form, are highly efficient for the N-arylation reaction. In the presence of cubic Cu2O nanoparticles, 1,10-phenanthroline, and tetrabutylammonium fluoride, a variety of nitrogen-containing heterocycles smoothly underwent N-arylation with aryl and heteroaryl halides at 110-145 °C to give the corresponding products in moderate to excellent yields. It is noteworthy that the reaction is conducted under solvent-free conditions. The reaction mechanism is also discussed.