165875-64-9

Basic information

• Product Name: (2S,3S)-2-Chloro-3-hydroxy-3-phenyl-propionic acid ethyl ester
• Synonyms: (2S,3S)-2-Chloro-3-hydroxy-3-phenyl-propionic acid ethyl ester
• CAS NO: 165875-64-9
• Molecular Weight: 228.675
• Mol File: 165875-64-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2S,3S)-2-Chloro-3-hydroxy-3-phenyl-propionic acid ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3S)-2-Chloro-3-hydroxy-3-phenyl-propionic acid ethyl ester(165875-64-9)
• EPA Substance Registry System: (2S,3S)-2-Chloro-3-hydroxy-3-phenyl-propionic acid ethyl ester(165875-64-9)

Safety Data

• Hazardous Substances Data: 165875-64-9(Hazardous Substances Data)

Upstream product

• 41381-97-9 ethyl 2-chloro-3-oxo-3-phenylpropionate 

Relevant articles and documents

A new enantioselective synthesis of glycidates via dynamic kinetic resolution of racemic 2-chloro-3-keto esters using chiral Ru (II) complexes

2-chloro-3-keto esters were quantitatively hydrogenated to syn and anti 2-chloro-3-hydroxyester by asymmetric hydrogenation with chiral ruthenium (II) catalysts prepared in-situ from (COD)Ru(2-methylallyl)2 in presence of atropisomeric ligands such as MeO-Biphep and Binap, giving enantioselectivity up to 99%, 2-chloro-3-hydroxy esters were treated with different bases to give (E)-and (Z)-2,3-epoxyalkanoates in 65-90% yields with 84-97% ee.