16718-11-9

Basic information

• Product Name: 3-(PHENYLTHIO)THIOPHENE
• Synonyms: 3-(PHENYLTHIO)THIOPHENE;BUTTPARK 62\11-03;Phenyl 3-thienyl sulphide;Phenyl-3-thienylsulfide;3-(phenylmercapto)thiophene;3-(Phenylsulphanyl)thiophene
• CAS NO: 16718-11-9
• Molecular Formula: C₁₀H₈S₂
• Molecular Weight: 192.3
• Mol File: 16718-11-9.mol
• Article Data: 14

Chemical Properties

• Boiling Point: 110 °C
• Flash Point: 111-112°C/0.6mm
• Appearance: /
• Density: 1.24 g/cm³
• Vapor Pressure: 0.00155mmHg at 25°C
• Refractive Index: 1.667
• CAS DataBase Reference: 3-(PHENYLTHIO)THIOPHENE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(PHENYLTHIO)THIOPHENE(16718-11-9)
• EPA Substance Registry System: 3-(PHENYLTHIO)THIOPHENE(16718-11-9)

Safety Data

• Safety Statements: S24/25:Avoid contact with skin and eyes.
• Hazardous Substances Data: 16718-11-9(Hazardous Substances Data)

Usage

General Description

3-(Phenylthio)thiophene is an organic compound with the molecular formula C10H8S2. It is a thiophene derivative with a phenylthio group attached at the 3-position. This chemical is commonly used in the synthesis of organic materials and as a building block for the creation of various pharmaceuticals and agrochemicals. 3-(Phenylthio)thiophene is also used in the manufacture of OLED materials and in organic electronic devices due to its high electron mobility and good stability. Additionally, it is utilized in research and development as a core component for the creation of new and innovative compounds for various applications in the fields of medicine, technology, and materials science. Overall, 3-(phenylthio)thiophene plays an important role in organic chemistry and has a wide range of potential applications in various industries.

InChI:InChI=1/C10H8S2/c1-2-4-9(5-3-1)12-10-6-7-11-8-10/h1-8H

Upstream product

• 24388-23-6 2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole 
• 872-31-1 3-Bromothiophene 
• 108-98-5 thiophenol 
• 98-09-9 benzenesulfonyl chloride 
• 10486-61-0 3-thienyl iodide 
• 873-55-2 sodium benzenesulfonate 
• 17249-80-8 3-chlorothiophene 
• 882-33-7 diphenyldisulfane 
• 188290-36-0 thiophene 
• 831-91-4 Benzyl phenyl sulfide 
• 6165-69-1 Thien-3-ylboronic acid 
• 931-59-9 benzenesulfenyl chloride 

Downstream Products

• 81028-81-1 3-Phenylsulfanyl-thiophene-2-carboxylic acid 

Relevant articles and documents

Electrochemistry Enabled Nickel-Catalyzed Selective C?S Bond Coupling Reaction

This work describes an electrochemical enabled nickel-catalyzed chemoselective C?S bond coupling protocol for the production of aryl sulfides and sulfones. By simply switching the nickel catalysts and electrodes, this electrochemical C?S bond coupling has demonstrated excellent redox activity, scalability and sustainability. Furthermore, the mechanism for this electrochemical cross-coupling reaction has been investigated.

Modified conditions for copper-catalyzed ipso-thiolation of arylboronic acid esters with thiosulfonates

An efficient ipso-thiolation of arylboronic acid esters with thiosulfonates has been achieved under mild and odorless conditions using a copper catalyst. The use of TMEDA and cesium fluoride as the ligand and base, respectively, dramatically facilitated the desired transformation. The method exhibited a broad substrate scope, which allowed for the expeditious synthesis of diverse aryl sulfides from easily available starting materials.

Nano CoCuFe2O4-catalyzed coupling reaction of arylboronic acid with amines and thiols: An atom-economic and ligand-free route to access unsymmetrical amines and sulfides

An efficient protocol was developed for the nano CoCuFe2O4-catalyzed C-N and C-S bond formation. By this catalytic system, both amine and sulfide-based structural motifs were formed efficiently in aryl halide-free route. The amination reaction of phenyl boronic acid with various types of amines was conducted under ligand-free conditions, in ethanol as a green solvent at 60°C. Unsymmetrical diaryl/aryl alkyl sulfide synthesis via the coupling reaction of arylboronic acids with thiols was also conducted. The nano cobalt-copper ferrite was used as a heterogenous efficient, inexpensive, magnetically separable and recyclable catalyst that can be used for several cycles.