167300-50-7

Basic information

• Product Name: benzylmethylenecyclopropane
• Synonyms: benzylmethylenecyclopropane
• CAS NO: 167300-50-7
• Molecular Weight: 144.216
• Mol File: 167300-50-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: benzylmethylenecyclopropane(CAS DataBase Reference)
• NIST Chemistry Reference: benzylmethylenecyclopropane(167300-50-7)
• EPA Substance Registry System: benzylmethylenecyclopropane(167300-50-7)

Safety Data

• Hazardous Substances Data: 167300-50-7(Hazardous Substances Data)

Upstream product

• 100-39-0 benzyl bromide 
• 6142-73-0 methylene cyclopropane 

Downstream Products

• 141536-36-9 1-bromo-3-(3'-benzylmethylenecyclopropyl)propane 

Relevant articles and documents

Radical Cyclisations of Methylenecyclopropane Derivatives

Radical cyclisations of various methylenecyclopropane derivatives have been studied and it has been found that methylenecyclopropyl propyl radicals undergo exclusive 5-exo cyclisation while methylenecyclopropyl butyl radicals give a mixture of products re

A Novel Sequence of Radical Rearrangements involving the 5-Exo Cyclisation of a 3-(Methylenecyclopropyl)propyl Radical

Radical 10, generated from the corresponding imidazolethiocarbonyl derivative 3 or the phenyl selenide 4, rearranges in a six-step process to give the cyclohexene 5, after reduction; this rearrangement sequence includes the selective 5-Exo cyclisation of