16776-73-1

Basic information

• Product Name: Benzamide, N-(iminophenylmethyl)-
• CAS NO: 16776-73-1
• Molecular Formula: C14H12N2O
• Molecular Weight: 224.262
• Mol File: 16776-73-1.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzamide, N-(iminophenylmethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzamide, N-(iminophenylmethyl)-(16776-73-1)
• EPA Substance Registry System: Benzamide, N-(iminophenylmethyl)-(16776-73-1)

Safety Data

• Hazardous Substances Data: 16776-73-1(Hazardous Substances Data)

Upstream product

• 888-71-1 3,5-diphenyl-1,2,4-oxadiazole 
• 55-21-0 benzamide 
• 100-47-0 benzonitrile 
• 698-16-8 benzohydroximoyl chloride 
• 932-90-1 Benzaldoxime 
• 3488-55-9 (Z)-N-benzyl-N'-hydroxybenzimidamide 
• 574-15-2 (E)-benzil monooxime 
• 25250-38-8 N-(chlorophenylmethylene)benzamide 
• 7664-41-7 ammonia 
• 7664-93-9 sulfuric acid 
• 15295-13-3 4,6-diphenyl-[1,2,3,5]oxathiadiazine 2,2-dioxide 
• 7732-18-5 water 
• 54433-20-4 N-benzoyl-N'-chloro-benzamidine 
• 4194-36-9 N-<(Phenylthioxo)-methyl>benzamide 

Downstream Products

• 16776-74-2 N,N'-dibenzoyl-benzamidine 
• 888-71-1 3,5-diphenyl-1,2,4-oxadiazole 
• 23449-14-1 Dimethyl 3,5-diphenyl-5,6-pyrimidinedicarboxylate 
• 90095-54-8 S,S-dimorpholino-N-(N'-benzimidoyl)sulfimide 
• 90095-58-2 1-oxo-2-(N-benzoylbenzimidoyl)-5-methyl-3,6-dihydro-1,2-thiazine 
• 90095-55-9 N-(N'-benzoylbenzimidoyl)dichlorosulfimide 
• 90095-57-1 N-(N'-benzoylbenzimidoyl)sulfinylamine 
• 493-77-6 2,4,6-triphenyl-1,3,5-triazine 
• 4115-15-5 3,5-diphenyl-[1,2,4]thiadiazole 
• 614-28-8 N-benzoylbenzamide 
• 7664-41-7 ammonia 
• 99806-08-3 ((3aR,9aS)-4-Methyl-2-phenyl-3a,4,9,9a-tetrahydro-imidazo[4,5-b]quinoxalin-1-yl)-phenyl-methanone 
• 90095-56-0 N,N-dichloro-N'-benzoylbenzamidine 
• 54433-20-4 N-chloro-N'-benzoylbenzamidine 

Relevant articles and documents

NBS-mediated practical cyclization of N-acyl amidines to 1,2,4-oxadiazoles via oxidative N?O bond formation

A reaction involving an efficient NBS-mediated oxidative N?O bond formation has been established for the synthesis of 1,2,4-oxadiazoles from readily accessible N-acyl amidines. The features of this synthetic method include simplicity of operation, mild re

Hydroxide-initiated conversion of aromatic nitriles to imidazolines: Fullerenes vs TCNE

Transformation of aromatic nitriles to imidazolines has been achieved under basic conditions with the electron-deficient C60 and C70 fullerenes, but not with the electron-deficient olefin of tetracyanoethylene (TCNE). In situ UV-vis-

Photoinduced molecular rearrangements. The photochemistry of 1,2,4-oxadiazoles in the presence of sulphur nucleophiles. Synthesis of 1,2,4-thiadiazoles

The photochemistry of some 1,2,4-oxadiazoles in the presence of sulphur nucleophiles has been investigated. Irradiation of the 5-amino-3-phenyl- and 3,5-diphenyl-1,2,4-oxadiazole at λ = 254 nm in methanol in the presence of sodium hydrogen sulphide or thiols gave a photo-induced redox reaction at the ring O-N bond, leading to the corresponding N-substituted benzamidines. By contrast, irradiation of the 5-amino-3-phenyl-1,2,4-oxadiazole in the presence of thioureas or thiocarbamates, essentially gave 3-phenyl-5-substituted 1,2,4-thiadiazoles, which presume an N-S bond formation between the ring-photolytic species and the sulphur nucleophile. In turn, irradiation of the same 5-amino-3-phenyl-1,2,4-oxadiazole in the presence of thioamides again afforded the redox reaction; in addition, amounts of 3-phenyl-5-substituted-1,2,4-thiadiazoles were also formed. Some mechanistic considerations are reported and synthetic methodologies leading to 1,2,4-thiadiazoles are emphasized.