16829-32-6

Basic information

• Product Name: Carbonofluoridothioicacid, anhydrosulfide with thiohypochlorous acid (9CI)
• Synonyms: Formylthiohypochlorite, fluoro- (8CI); Fluorocarbonylsulfenyl chloride; Formyl fluoride,(chlorothio)-
• CAS NO: 16829-32-6
• Molecular Formula: CCl F O S
• Molecular Weight: 114.528
• Mol File: 16829-32-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Carbonofluoridothioicacid, anhydrosulfide with thiohypochlorous acid (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Carbonofluoridothioicacid, anhydrosulfide with thiohypochlorous acid (9CI)(16829-32-6)
• EPA Substance Registry System: Carbonofluoridothioicacid, anhydrosulfide with thiohypochlorous acid (9CI)(16829-32-6)

Safety Data

• Hazardous Substances Data: 16829-32-6(Hazardous Substances Data)

Upstream product

• 108391-95-3 2,4-Dichlor-2,4-difluor-1,3-dithietan-1,3-dioxids 

Downstream Products

• 463-58-1 carbon oxide sulfide 
• 51615-87-3 Fluorcarbonylsulfensaeure-N-methyl-N-phenylamid 
• 51615-85-1 Phenylfluorcarbonyldisulfon 
• 27961-70-2 Fluorcarbonyl-sulfenyl-trifluoracetat 
• 26555-40-8 metgoxycarbonylsulfenyl chloride 
• 51615-86-2 Fluorcarbonylsulfensaeure-N,N-diphenylamid 
• 26555-35-1 ethoxyoxomethanesulfenyl chloride 
• 51093-54-0 3-fluoro-2-isopropyl-2H-[1,2,4]thiadiazol-5-one 

Relevant articles and documents

Characterisierung und Photochemie von (Dihalogenmethylen)sulfoxiden, XYC=S=O

Dihalogenomethylene sulfoxides (dihalogenosulfines) 2a-c were generated by flash vacuum pyrolysis of 2,2,4,4-tetrahalogeno-1,3-dithietane 1,3-dioxides 1a-c and trapping the pyrolysis products in argon at 10 K.At room temperature unstable difluorosulfine (2a) and chlorofluorosulfine (2b) were identified by i.r.spectroscopy, and the photochemistry of the sulfines was investigated.Chlorofluorosulfine (2b) exists in two geometrical isomers.Photolysis of 2a leads to fragmentation to give CF2 and SO, photolysis of the chlorine containing sulfines 2b and 2c to rearrangement to give sulfenyl chlorides 6 and 8.This is explained by different migratory tendencies of fluorine and chlorine and the stability of C-F bond.