16894-68-1

Basic information

• Product Name: Stibonium, tetraphenyl-, chloride
• CAS NO: 16894-68-1
• Molecular Formula: C24H20Sb.Cl
• Molecular Weight: 465.626
• Mol File: 16894-68-1.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Stibonium, tetraphenyl-, chloride(CAS DataBase Reference)
• NIST Chemistry Reference: Stibonium, tetraphenyl-, chloride(16894-68-1)
• EPA Substance Registry System: Stibonium, tetraphenyl-, chloride(16894-68-1)

Safety Data

• Hazardous Substances Data: 16894-68-1(Hazardous Substances Data)

Upstream product

• 105242-73-7 1,1,1-triphenyl-2,1λ(5)-benzoxabismol-3(1H)-one 
• 603-36-1 triphenylantimony 
• 2170-05-0 pentaphenylantimony 
• 753-73-1 dimethyltin dichloride 
• 1066-45-1 trimethyltin(IV)chloride 
• 100-56-1 phenylmercury(II) chloride 
• 1461-22-9 tributyltin chloride 
• 1135-99-5 diphenyltin(IV) dichloride 
• 2170-05-0 pentaphenylantimony 
• 866-55-7 dichlorodiethylstannane 
• 994-31-0 chlorotriethylstannane 
• 2279-76-7 tripropyltin chloride 
• 2373-51-5 chloro-methylsulfanyl-methane 
• 528-76-7 2,4-dinitrobenzenesulfenyl chloride 

Downstream Products

• 603-36-1 triphenylantimony 
• 103-26-4 methyl cinnamate 
• 119305-89-4 (C₆H₅)4SbOOCC₆H₄COOSb(C₆H₅)4 
• 13903-91-8 tetraphenyl stibonium iodide 
• 84219-95-4 (C₆H₅)4Sb⁽¹⁺⁾*VCl₄^(1-)=(C₆H₅)4SbVCl₄ 
• 79110-45-5 [(C₆H₅)4Sb]⁽¹⁺⁾*[TiCl₅]^(1-)=[(C₆H₅)4Sb][TiCl₅] 
• 925457-75-6 YbCl₂(C₄H₈O)4 
• 925457-71-2 YbCl(C₄H₈O)4(C₆H₅C₂) 
• 16894-73-8 tetraphenylantimony chlorate 
• 1259321-95-3 cis-dichloro(triphenylstibine)(dimethylsulfoxide)platinum(II) 

Relevant articles and documents

Catalytic C-phenylation of methyl acrylate with tetraphenylantimony(v) halides and carboxylates

Catalytic C-phenylation of methyl acrylate to methyl cinnamate with the Ph4SbX complexes (X = F, Cl, Br, OH, OAc, O2CEt) in the presence of the palladium compounds PdCl2, Pd(OAc)2, Pd2(dba)3, Pd(Ph3P)2Cl2, and Pd(dppf)Cl2 (dba is dibenzylideneacetone and dppf is bis(diphenylphosphinoferrocene)) was studied in organic solvents (MeCN, THF, DMF, MeOH, and AcOH). The highest yield of methyl cinnamate (73% based on the starting organometallic compound) was obtained for the Ph4SbCl- PdCl2 (1:0.04) system in acetonitrile.

Reactions of pentaphenylantimony and pentaphehylphosphorus with arylmercury chlorides [3]

-

Arylation of organotin halides with pentaarylantimony and pentaphenylbismuth

Pentaarylantimony and pentaphenylbismuth arylate oranotin halides R3SnX and R2SnX2 (R = Alk, Ar; X = Cl, Br) in toluene at room temperature to aryltin derivatives R3SnAr and R2SnArX (initial reagent molar ratio 1:1) or R2SnAr2 (2:1) in 78-95% yield.