16906-70-0

Basic information

• Product Name: Carbamodithioic acid, dimethyl-, phenyl ester
• CAS NO: 16906-70-0
• Molecular Formula: C9H11NS2
• Molecular Weight: 197.325
• Mol File: 16906-70-0.mol
• Article Data: 29

Chemical Properties

• CAS DataBase Reference: Carbamodithioic acid, dimethyl-, phenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamodithioic acid, dimethyl-, phenyl ester(16906-70-0)
• EPA Substance Registry System: Carbamodithioic acid, dimethyl-, phenyl ester(16906-70-0)

Safety Data

• Hazardous Substances Data: 16906-70-0(Hazardous Substances Data)

Upstream product

• 591-50-4 iodobenzene 
• 137-26-8 Thiram 
• 97-74-5 bis(dimethylthiocarbamoyl)sulfide 
• 98-80-6 phenylboronic acid 
• 75-15-0 carbon disulfide 
• 88284-48-4 2-(trimethylsilyl)phenyl trifluoromethanesulfonate 
• 124-40-3 dimethyl amine 
• 369-57-3 benzenediazonium tetrafluoroborate 
• 882-33-7 diphenyldisulfane 
• 128-04-1 sodium dimethyldithiocarbamate 
• 312727-69-8 phenyl(2,4,6-triisopropylphenyl)iodonium trifluoromethanesulfonate 
• 144930-50-7 mesityl(phenyl)iodonium triflouromethanesulfonate 
• 722-56-5 diphenyliodonium nitrate 
• 1483-72-3 diphenyliodonium chloride 

Downstream Products

• 7304-68-9 phenyl N,N-dimethyl(thiocarbamate) 
• 1115-06-6 dimethylthiocarbamoyl dimethylcarbamoyl disulfide 
• 20057-88-9 diphenyl trisulfide 
• 53144-50-6 diphenyl tetrasulfide 
• 882-33-7 diphenyldisulfane 
• 149019-85-2 3-(2-methoxyphenyl)-1,1-dimethyl-thiourea 
• 705-62-4 N,N-dimethyl-N'-phenylthiourea 
• 2741-13-1 3,3-dimethyl-1-(4-methylphenyl)thiourea 
• 75104-96-0 6-bromo-N,N-dimethylbenzo[d]thiazol-2-amine 
• 75104-97-1 N,N,6-trimethylbenzo[d]thiazol-2-amine 

Relevant articles and documents

Copper(II)-Promoted Cascade Synthesis of 2-Aminobenzothiazoles Starting from 2-Iodoanilines and Sodium Dithiocarbamates

A facile and efficient formation of 2-aminobenzothiazoles by a copper(II)-promoted one-pot cascade process was developed. The desired 2-aminobenzothiazoles were synthesized in good to excellent yields (up to 97 %) in the presence of Cu(OAc)2 an

Synthesis of Aryl Dithiocarbamates from Tetramethylthiuram Monosulfide (TMTM) and Aryl Boronic Acids: Copper-Catalyzed Construction of C(sp2)-S Bonds

A highly efficient method for the synthesis of S-aryl dithiocarbamates is reported. By using tetramethylthiuram monosulfide (TMTM) and aryl boronic acids as starting materials, C(sp2)-S bondforming reactions proceed smoothly to give the desired aryl dithiocarbamates in good to excellent yields. The methodology features a simple procedure, broad functional group tolerance and excellent yields, whilst showing potential synthetic value for the preparation of a diverse range of biologically and pharmaceutically active compounds.

Copper-Catalyzed Synthesis of S-Aryl Dithiocarbamates from Tetraalkylthiuram Disulfides and Aryl Iodides in Water

An efficient approach for the copper-catalyzed synthesis of aryl dithiocarbamates from aryl iodides and tetraalkylthiuram disulfides in water is described. Without additional ligand and organic solvent, the coupling reaction could provide a series of S-aryl dithiocarbamates in moderate to good yields.

Chemoselective C–S/S–S Formation between Diaryl Disulfides and Tetraalkylthiuram Disulfides

An efficient C–S/S–S formation for the chemoselective synthesis of aryl dithiocarbamate (C–S formation) and aryl dialkylcarbamo(dithioperoxo)thioate (S–S formation) was studied. The chemoselectivity could be controlled by modulating the reaction temperature, base, and catalyst. The transformation features a simple reaction, easily available starting materials, high selectivity and easy performance, showing its practical synthetic value for the preparation of some potential biologically or pharmaceutically active compounds.