16913-61-4

Basic information

• Product Name: dimethyl-dithiocarbamic acid 4-chloro-phenyl ester
• Synonyms: dimethyl-dithiocarbamic acid 4-chloro-phenyl ester
• CAS NO: 16913-61-4
• Molecular Weight: 231.77
• Mol File: 16913-61-4.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: dimethyl-dithiocarbamic acid 4-chloro-phenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: dimethyl-dithiocarbamic acid 4-chloro-phenyl ester(16913-61-4)
• EPA Substance Registry System: dimethyl-dithiocarbamic acid 4-chloro-phenyl ester(16913-61-4)

Safety Data

• Hazardous Substances Data: 16913-61-4(Hazardous Substances Data)

Upstream product

• 34220-01-4 di-(4-chlorophenyl)iodonium chloride 
• 128-04-1 sodium dimethyldithiocarbamate 
• 106-54-7 p-Chlorothiophenol 
• 16420-13-6 N,N-Dimethylthiocarbamoyl chloride 
• 637-87-6 1-Chloro-4-iodobenzene 
• 75-15-0 carbon disulfide 
• 106-47-8 4-chloro-aniline 
• 124-40-3 dimethyl amine 
• 137-26-8 Thiram 
• 1679-18-1 4-Chlorophenylboronic acid 
• 673-41-6 p-chlorobenzenediazonium tetrafluoroborate 
• 97-74-5 bis(dimethylthiocarbamoyl)sulfide 

Downstream Products

• 22865-55-0 (4-chlorophenyl)(4-methylphenyl)sulfane 
• 20912-69-0 (4-chlorophenyl)-(4-methoxyphenyl)sulfane 
• 5181-10-2 bis(4-chlorophenyl)sulfide 
• 24535-57-7 1-bromo-4-(4-chlorophenylsulfanyl)-benzene 
• 127567-57-1 (4-chlorophenyl)(naphthalen-1-yl)sulfane 

Relevant articles and documents

Synthesis of Aryl Dithiocarbamates from Tetramethylthiuram Monosulfide (TMTM) and Aryl Boronic Acids: Copper-Catalyzed Construction of C(sp2)-S Bonds

A highly efficient method for the synthesis of S-aryl dithiocarbamates is reported. By using tetramethylthiuram monosulfide (TMTM) and aryl boronic acids as starting materials, C(sp2)-S bondforming reactions proceed smoothly to give the desired aryl dithiocarbamates in good to excellent yields. The methodology features a simple procedure, broad functional group tolerance and excellent yields, whilst showing potential synthetic value for the preparation of a diverse range of biologically and pharmaceutically active compounds.

Aryldithiocarbamates as thiol alternatives in Cu-catalyzed C(aryl)-S coupling reactions using aryldiazonium tetrafluoroborate salts

An efficient method for the synthesis of unsymmetrical diaryl sulfides has been developed by the C-S cross coupling of aryldithiocarbamates and aryldiazonium salts in the presence of CuI-2,2′-bipyridine and Zn. Aryldithiocarbamate compounds have been used here as thiol substitutes. The protocol shows wide substrate scope and good yields of the products.

Synthesis of Phenyl Dithiocarbamates Starting from Sodium Dialkyldithiocarbamates and Aryl Boronic Acids: a Copper Catalyzed S-Arylation

A convenient and efficient protocol for the S-arylation of sodium dialkyldithiocarbamates was developed. With the catalysis of copper(I) bromide, sodium dialkyldithiocarbamates coupled with aryl boronic acids giving the C-S coupling products smoothly in g