169170-03-0

Basic information

• Product Name: N-methyl-N-phenylanthranilic acid methyl ester
• Synonyms: N-methyl-N-phenylanthranilic acid methyl ester
• CAS NO: 169170-03-0
• Molecular Weight: 241.29
• Mol File: 169170-03-0.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: N-methyl-N-phenylanthranilic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: N-methyl-N-phenylanthranilic acid methyl ester(169170-03-0)
• EPA Substance Registry System: N-methyl-N-phenylanthranilic acid methyl ester(169170-03-0)

Safety Data

• Hazardous Substances Data: 169170-03-0(Hazardous Substances Data)

Upstream product

• 88-65-3 2-bromobenzoic-acid 
• 121-69-7 N,N-dimethyl-aniline 
• 124-38-9 carbon dioxide 
• 613-97-8 N-methyl-N-ethylaniline 
• 88284-48-4 2-(trimethylsilyl)phenyl trifluoromethanesulfonate 
• 91-66-7 N,N-diethylaniline 
• 610-94-6 2-bromobenzoic acid methyl ester 
• 35708-19-1 Methyl N-phenylanthranilate 
• 74-88-4 methyl iodide 
• 10072-05-6 methyl 2-(dimethylamino)benzoate 
• 88-67-5 2-Iodobenzoic acid 
• 62-53-3 aniline 
• 77-78-1 dimethyl sulfate 
• 118-91-2 ortho-chlorobenzoic acid 

Downstream Products

• 1290129-55-3 10,10'-dimethyl-9,9,9',9'-tetraphenyl-9,9',10,10'-tetrahydro-2,2'-biacridine 
• 20474-14-0 9,9-diphenyl-10-methyl-9,10-dihydroacridine 
• 719-54-0 10-methyl-9, 10-dihydro-9-acridinone 
• 30713-65-6 9-hydroxy-9,10-dihydro-10-methylacridine 
• 1541201-37-9 N-methoxy-2-(methyl(phenyl)amino)benzamide 
• 1541201-52-8 2-(methyl(phenyl)amino)-N-phenylbenzamide 
• 1541201-35-7 5-methyl-10-phenyl-5H-dibenzo[b,e][1,4]diazepin-11(10H)-one 
• 5026-42-6 5,10-dihydro-5-methyl-11H-dibenzo[b,e][1,4]diazepin-11-one 
• 73323-82-7 2-(N-Methyl-N-phenylamino)-benzoic acid 
• 16095-32-2 1-phenyl-1,2-dihydro-4H-benzo[d][1,3]oxazin-4-one 
• 1484-12-4 N-methylcarbazole 
• 169169-80-6 N-Methyl 9,9-bis-(4-hydroxyphenyl)-(9H)-acridine 
• 208664-53-3 2-((N-methyl-N-phenyl)amino)benzaldehyde 
• 208664-59-9 C₂₁H₂₁N₃O₃S 

Relevant articles and documents

Redox-neutral decarboxylative photocyclization of anthranilic acids

A mild metal-, catalyst-, and oxidant-free photoredox neutral system has been found to efficiently enable intramolecular decarboxylative cyclization of anthranilic acids. This facile protocol provides an alternative method for the synthesis of carbazoles. Mechanistic studies reveal a key photoinduced 6π-electrocyclization process and formic acid was released as the sole byproduct.

PhI(OAc)2-mediated intramolecular oxidative aryl-aldehyde C sp 2-C sp 2 bond formation: Metal-free synthesis of acridone derivatives

A metal-free protocol for direct aryl-aldehyde Csp2-Csp 2 bond formation via a PhI(OAc)2-mediated intramolecular cross-dehydrogenative coupling (CDC) of various 2-(N-arylamino)aldehydes was developed. The novel methodology requires no need of preactivation of the aldehyde group, is applicable to a large variety of functionalized substrates, and most of all provides a convenient approach to the construction of biologically important acridone derivatives.

TRANSITION-METAL-FREE N-ARYLATION OF TERTIARY AMINES USING ARYNES

The present invention relates to transition-metal-free process for the synthesis of tertiary arylamines comprises coupling reaction between arynes and N,N-dimethyl aniline compounds in presence of 18-crown-6, KF and THF.