16936-56-4

Basic information

• Product Name: Benzene, 1-chloro-4-(trichloromethoxy)-
• CAS NO: 16936-56-4
• Molecular Formula: C7H4Cl4O
• Molecular Weight: 245.92
• Mol File: 16936-56-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzene, 1-chloro-4-(trichloromethoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-chloro-4-(trichloromethoxy)-(16936-56-4)
• EPA Substance Registry System: Benzene, 1-chloro-4-(trichloromethoxy)-(16936-56-4)

Safety Data

• Hazardous Substances Data: 16936-56-4(Hazardous Substances Data)

Upstream product

• 623-12-1 4-chloromethoxybenzene 
• 21151-56-4 p-chlorophenoxymethyl chloride 
• 56-23-5 tetrachloromethane 
• 106-48-9 4-chloro-phenol 
• 1124-59-0 4-chlorophenyl cyanate 
• 29164-55-4 perchloro-2-aza-1-propene 
• 461-81-4 1-chloro-4-(trifluoromethoxy)benzene 

Downstream Products

• 24641-61-0 O-(4-chlorophenyl) thiocarbamate 
• 461-80-3 chlorodifluoromethyl p-chlorophenyl ether 
• 461-81-4 1-chloro-4-(trifluoromethoxy)benzene 
• 16936-62-2 Tribrommethyl-(4-chlorphenyl)-aether 
• 24572-47-2 p-ClC₆H₄OC(S)F 
• 50844-36-5 C₁₀H₄Cl₆N₂O 

Relevant articles and documents

Formation of Dichloromethyl Phenyl Ethers as Major Products in Photo-Reimer-Tiemann Reaction without Base

Photolysis of phenols 1a-d in chloroform or carbon tetrachloride afforded the corresponding di- or trichloromethyl phenyl ethers (2a-d or 6a-d, respectively).In chloroform, hydroxybenzaldehydes 4a-d or 5 and phenyl formates 3a-d were obtained as minor photoproducts.In carbon tetrachloride, traces of salicyloyl chloride (7), phenyl salicylate (8) and phenyl p-hydroxybenzoate (9) were detected starting from the parent phenol (1a).The obtained results agree with the involvement of an electron transfer mechanism.