17009-86-8Relevant articles and documents
Experimental and Theoretical Studies of the Gas-Phase Protonation of Vinyl Ethers, Vinyl Sulfides, and Vinyl Selenides
Oesapay, K.,Delhalle, J.,Nsunda, K. M.,Rolli, E.,Houriet, R.,Hevesi, L.
, p. 5028 - 5036 (2007/10/02)
A series of nine chalcogen-substituted ethylenes (chalcogen = O, S, Se) have been synthesized, and their gas-phase proton affinities (PA) were determined experimentally by measuring gas-phase basicities (GB) in an ion cyclotron resonance (ICR) spectrometer and theoretically by means of ab initio MO calculations at the STO-3G and 3-21G* levels.A satisfactory correlation (r = 0.978, slope = 1.41) has been obtained between the experimental and calculated 3-21G(*) values.In contrast with a number of previous reports, we consistently found that third- (SMe) and fourth-row (SeMe) substituents do not stabilize better the adjecent positive charge than does the second-row substituent OMe, even in the gas phase.In fact, comparison of experimental proton affinity value of ethylene with that of mono(methylchalco)ethylenes indicates that OMe, SMe, and SeMe groups stabilize the corresponding ethyl cations to very much the same extent.In 2-propyl cations the trend is O > S > Se, but the differences (δΔ in Table III) are quite small: 1.2 kcal mol-1 between O and S and 1.4 kcal mol-1 between S and Se.The superior ability of oxygen in carbenium ion stabilization appears the most clearly in the protonation of bis(methylchalco)ethylenes: dimethoxyethyl cation is more stable than the corresponding thio species by ca. 5.5 kcal mol-1, whereas dithio- and diselenocarbenium ions again have very similar stabilities.These conclusions are supported and extended by ab initio results on optimized geometries.
Oxonium Ions. Solvation by Single Acetonitrile Molecules in the Gas Phase and by Bulk Solvents
Bromilow, J.,Abboud, J. L. M.,Lebrilla, C. B.,Taft, R. W.,Scorrano, G.,Lucchini V.
, p. 5448 - 5453 (2007/10/02)
The standard free energy of formation of gaseous complexes between monoprotonic oxonium ions and acetonitrile have been obtained by using the ion cyclotron resonance equilibrium constant method for exchange of acetonitrile between the ions.The results show that the "solvation" by a single molecule of acetonitrile in the gas phase reproduces the important diverse effects of molecular structure on oxonium ion solvation by bulk water.It is estimated from the present results that the effects of solvation by bulk water are only about three times as great as the corresponding effects of "solvation" by a single water molecule in the gas phase.Internal charge delocalization from the protonic site of the oxonium ions may be reversed by differential solvation, both with single H-bonding molecules in the gas phase and with bulk solvent.Further evidence for the site of preffered protonation of esters and amides is provided.
