17015-15-5

Basic information

• Product Name: AC-GLU-OME
• Synonyms: N-ALPHA-ACETYL-L-GLUTAMIC ACID ALPHA-METHYL ESTER;AC-GLUTAMIC ACID-OME;AC-GLU-OME;ACETYL-L-GLUTAMIC ACID ALPHA-METHYL ESTER;N-Acetyl-L-glutamic acid 1-methyl ester;Acetyl-L-glutamic acid α-methyl ester≥ 95% (NMR);Ac-L-Glu-OMe
• CAS NO: 17015-15-5
• Molecular Formula: C₈H₁₃NO₅
• Molecular Weight: 203.19
• Mol File: 17015-15-5.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 443.513 °C at 760 mmHg
• Flash Point: 222.029 °C
• Appearance: /
• Density: 1.231 g/cm³
• Storage Temp.: 2-8°C
• Solubility: DMSO (Slightly), Ethanol (Slightly), Methanol (Slightly)
• PKA: 4.42±0.10(Predicted)
• CAS DataBase Reference: AC-GLU-OME(CAS DataBase Reference)
• NIST Chemistry Reference: AC-GLU-OME(17015-15-5)
• EPA Substance Registry System: AC-GLU-OME(17015-15-5)

Safety Data

• Hazardous Substances Data: 17015-15-5(Hazardous Substances Data)

Usage

Chemical Properties

Colorless oil

Upstream product

• 6234-01-1 L-glutamic acid 5-tert-butyl 1-methyl ester hydrochloride 
• 108-24-7 acetic anhydride 

Downstream Products

• 1391027-75-0 C₂₉H₄₀N₄O₁₂S 
• 936952-62-4 C₂₃H₃₂N₄O₁₀S 
• 936952-13-5 C₃₁H₄₄N₄O₁₂S₂ 

Relevant articles and documents

Photodecarboxylative Amination of Redox-Active Esters with Diazirines

Diazirines have been recently demonstrated to serve as electrophilic amination reagents that afford diaziridines, versatile heterocycles that are readily transformed into amines, hydrazines, and nitrogen-containing heterocycles. Here, we report the photodecarboxylative amination of redox-active esters with diazirines using inexpensive photoactivators under mild conditions with an enhanced scope for primary substrates. The stability of diazirines to blue light is demonstrated, paving the way for further research into other photochemical amination methods with these unique heterocycles.