170502-12-2

Basic information

• Product Name: phenylsulfanylacetic acid 5'-methyl-2'-(1'-methyl-1'-phenylethyl)-cyclohexyl ester
• Synonyms: phenylsulfanylacetic acid 5'-methyl-2'-(1'-methyl-1'-phenylethyl)-cyclohexyl ester
• CAS NO: 170502-12-2
• Molecular Weight: 382.567
• Mol File: 170502-12-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: phenylsulfanylacetic acid 5'-methyl-2'-(1'-methyl-1'-phenylethyl)-cyclohexyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: phenylsulfanylacetic acid 5'-methyl-2'-(1'-methyl-1'-phenylethyl)-cyclohexyl ester(170502-12-2)
• EPA Substance Registry System: phenylsulfanylacetic acid 5'-methyl-2'-(1'-methyl-1'-phenylethyl)-cyclohexyl ester(170502-12-2)

Safety Data

• Hazardous Substances Data: 170502-12-2(Hazardous Substances Data)

Upstream product

• 7031-27-8 (phenylthio)acetic acid chloride 
• 65253-04-5 (-)-8-phenylmenthol 
• 103-04-8 (phenylthio)acetic acid 

Downstream Products

• 1026955-70-3 (-)-8-phenylmenthyloxycarbonyl-α-(phenylthio)methyl chloride 

Relevant articles and documents

Asymmetric Friedel-Crafts alkylation using chiral α-acyl-α-chloromethylsulphides

Lewis acid catalysed stereoselective Friedel-Crafts alkylation of aromatic compounds with α-(-)-menthyloxycarbonyl-α-(phenylthio)methyl chloride and α-(-)-8-phenylmenthyloxycarbonyl-α-(phenylthio)methyl chloride is described. Copyright (C) 2000 Elsevier Science Ltd.

Electrolytic partial fluorination of organic compounds. Part 15. Stereochemical study of the anodic monofluorination of α-phenylsulfenyl acetates

The diastereoselective anodic fluorination of α-phenylsulfenyl esters by intramolecular asymmetry-induction has been studied using chiral auxiliaries such as phenethyl, bornyl, isobornyl, menthyl and 8-phenylmenthyl groups.Of these chiral auxiliaries, the 8-phenylmenthyl group gave the best diastereoselectivity.The diastereoselectivity was also affected by supporting electrolytes and it was found that Et4NF*3HF showed better selectivity in comparison to Et3N*3HF and Et3N*2HF. - Keywords: Electrolytic partial fluorination; Organic compounds; α-phenylsulfenyl acetates; Diastereoselectivity; Chiral fluorocompounds