17067-71-9Relevant articles and documents
Synthesis and structural characterization of carbon-centered tris(pentafluorophenyl)silyl derivatives
Dilman, Alexander D.,Arkhipov, Dmitry E.,Korlyukov, Alexander A.,Ananikov, Valentine P.,Danilenko, Vitalij M.,Tartakovsky, Vladimir A.
, p. 3680 - 3689 (2007/10/03)
A general method for the synthesis of carbon-centered tris(pentafluorophenyl)silyl derivatives (RSi(C6F5) 3) by reaction of trichlorosilanes (RSiCl3) with pentafluorophenylmagnesium bromide was described. The cr
Preparation of halogeno(pentafluorophenyl)silanes (C6F5)nSiX4-n (X=F, Cl and Br; N=2, 3) from pentafluorophenyl(phenyl)silanes (C6F5)nSiPh4-n
Frohn,Lewin,Bardin
, p. 233 - 240 (2007/10/03)
Halogeno(pentafluorophenyl)silanes (C6F5)nSiX4-n (X=F, Cl and Br; n=2, 3) were prepared in good yields from the corresponding phenylsilanes (C6F5)nSiPh4-n by reactions with the electrophiles aHF, FSO3H, HCl-AlCl3 or with AlX3 (X=Cl, Br)-halogenated hydrocarbons. The relative leaving ability of the organyl groups (C6F5, C6H5, Me) bonded to the silicon atom and the strength of the electrophilic reagent are discussed.