17096-29-6

Basic information

• Product Name: 4-[(4-amino-2-chloro-phenyl)methyl]-3-chloro-aniline
• Synonyms: 4-[(4-amino-2-chloro-phenyl)methyl]-3-chloro-aniline;4,4'-Methylenebis(3-chloroaniline);4,4'-Methylenebis(3-chlorobenzenamine)
• CAS NO: 17096-29-6
• Molecular Formula: C₁₃H₁₂Cl₂N₂
• Molecular Weight: 267.15
• Mol File: 17096-29-6.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 451.6°Cat760mmHg
• Flash Point: 226.9°C
• Appearance: /
• Density: 1.354g/cm³
• CAS DataBase Reference: 4-[(4-amino-2-chloro-phenyl)methyl]-3-chloro-aniline(CAS DataBase Reference)
• NIST Chemistry Reference: 4-[(4-amino-2-chloro-phenyl)methyl]-3-chloro-aniline(17096-29-6)
• EPA Substance Registry System: 4-[(4-amino-2-chloro-phenyl)methyl]-3-chloro-aniline(17096-29-6)

Safety Data

• Hazardous Substances Data: 17096-29-6(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H12Cl2N2/c14-12-6-10(16)3-1-8(12)5-9-2-4-11(17)7-13(9)15/h1-4,6-7H,5,16-17H2

Upstream product

• 67-68-5 dimethyl sulfoxide 
• 108-42-9 3-chloro-aniline 
• 1817-74-9 bis(4-nitrophenyl)methane 
• 141-85-5 3-chloroaniline hydrochloride 
• 62001-31-4 N-((1H-benzo[d][1,2,3]triazol-1-yl)methyl)-3-chloroaniline 
• 50-00-0 formaldehyd 
• 71669-07-3 bis-(2-chloro-4-nitro-phenyl)-methane 

Relevant articles and documents

Highly regioselective para-methylthiolation/bridging methylenation of arylamines promoted by NH4I

Aryl methyl thioethers and methylene-bridged arylamines were synthesized via highly regioselective para-methylthiolation/bridging methylenation of arylamines using DMSO as the methylthio or methylene source in the presence of NH4I under metal-free conditions. For the substrates with both electron-donating and electron-withdrawing substituents, the reaction proceeded smoothly and gave moderate to good yields.

Benzotriazole Mediated Synthesis of Methylenebisanilines

Methylenebisanilines and methylenebis(N,N-dialkylaniline)s are prepared by the reactions of 1-hydroxymethylbenzotriazole with anilines and with N,N-dialkylanilines under acidic conditions.Isolation of the intermediate 4-(benzotriazol-1-ylmethyl)anilines and the N,N-dialkyl analogues and their reactions with anilines allow the efficient preparation of both symmetrical and unsymmetrical members of both product classes.