171018-16-9Relevant articles and documents
Syntheses of Chelating Tetrazole-Containing Ligands and Studies of Their Palladium(II) and Ruthenium(II) Complexes
Downard, Alison J.,Steel, Peter J.,Steenwijk, Jonathan
, p. 1625 - 1642 (1995)
Eleven chelating tetrazole-containing ligands have been synthesized, and their complexes with palladium(II) and ruthenium(II) prepared.Proton n.m.r. spectroscopy, electronic absorption spectroscopy and cyclic voltammetry have been used to study the nature of the metal-ligand interactions in these complexes.The negatively charged tetrazolate group is shown to be a strong electron donor with very different properties to those of the protonated or alkylated tetrazole group.This leads to pH control of the properties of transition metal complexes containing such ligands.
Alkyl tetrazoles as diimine (“diim”) ligands for fac-[Re(diim)(CO)3(L)]-type complexes. Synthesis, characterization and preliminary studies of the interaction with bovine serum albumin
Monti, Nicola,Longo, Veronica,Zacchini, Stefano,Vigarani, Giulia,Giorgini, Loris,Bonora, Eugenia,Massi, Massimiliano,Fiorini, Valentina,Stagni, Stefano
, (2021)
Herein, we report a new family of luminescent Re(I) complexes with general formula fac-[Re(diim)(CO)3L]0/+ in which the role of the diimine-type chelating ligand (diim) is played by alkylated tetrazoles. In particular, the design of