17151-51-8 Usage
Description
1,4-Phenylenebis[tributylstannane] is an organostannane compound with the molecular formula C32H72Sn2. It is characterized by its two tributylstannane groups connected through a 1,4-phenylene bridge. 1,4-Phenylenebis[tributylstannane] is known for its unique chemical properties and potential applications in various fields.
Uses
1. Used in Chemical Synthesis:
1,4-Phenylenebis[tributylstannane] is used as a reactant for the preparation of covalent analogs of DNA base pairs and triplets from 9-benzyl-6-chloropurine via a Stille cross-coupling reaction. This application is significant in the development of novel DNA analogs with potential applications in molecular biology and drug design.
2. Used in Pharmaceutical Industry:
In the pharmaceutical industry, 1,4-Phenylenebis[tributylstannane] is used as a reactant for the reaction with glucuronolactone derivatives. This reaction leads to the preparation of 3-C-iodomethyl, 6-C-iodomethyl, and 6-C-iodophenyl derivatives, which are higher iodinated analogs of D-glucose. These analogs have potential applications in the development of new drugs and therapeutic agents.
3. Used in Organic Chemistry Research:
1,4-Phenylenebis[tributylstannane] is also utilized in organic chemistry research as a versatile reagent for various chemical transformations. Its unique structure allows for the exploration of new synthetic pathways and the development of innovative chemical processes.
Check Digit Verification of cas no
The CAS Registry Mumber 17151-51-8 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,7,1,5 and 1 respectively; the second part has 2 digits, 5 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 17151-51:
(7*1)+(6*7)+(5*1)+(4*5)+(3*1)+(2*5)+(1*1)=88
88 % 10 = 8
So 17151-51-8 is a valid CAS Registry Number.
17151-51-8Relevant articles and documents
π-electron conjugated compound, manufacturing method therefor, and π-electron conjugated polymer obtained using same
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Page/Page column 36, (2013/08/28)
Provided are a π-electron conjugated polymer having a constitutional unit represented by general formula (2) that is suitable as an electrochromic material that changes from a desired colored state to a decolored state, a new compound that is a raw materi
Distannylation of strained carbon-carbon triple bonds catalyzed by a palladium complex
Yoshida, Hiroto,Tanino, Kenji,Ohshita, Joji,Kunai, Atsutaka
, p. 5052 - 5055 (2007/10/03)
Oxidative addition of a distannane to a palladium(0) complex occurs during the distannylation of in situ generated arynes with distannanes in the presence of a catalytic amount of a palladium/tert-octyl isocyanide (tOcNC) complex to give 1,2-distannylarenes in moderate to high yields (see scheme). Bisarynes and cyclohexynes can also be used as substrates for the reaction.
Reaction of Arylboronic Acids and their Derivatives with Lead Tetra-acetate. The Generation of Aryl-lead Triacetates, and meta- and para-Phenylenebis(lead triacetate), in situ for Electrophilic Arylation
Morgan, Jacqueline,Pinhey, John T.
, p. 715 - 720 (2007/10/02)
Arylboronic acids and some of their derivatives have been found to undergo a rapid boron-lead exchange with lead tetra-acetate.In the presence of a catalytic amount of mercury(II) acetate, the reaction produces mainly the aryl-lead triacetate, and it has been developed as a convenient method for in situ generation of these useful electrophilic C-arylating reagents.The reaction allows the generation for the first time of meta- and para-phenylenebis(lead triacetate), compounds which behave as meta- and para-phenylene dication equivalents.
