171734-48-8

Basic information

• Product Name: tert-butyl(dimethyl)({(1S)-4-[(trimethylsilyl)oxy]cyclohex-3-en-1-yl}oxy)silane
• Synonyms: tert-butyl(dimethyl)({(1S)-4-[(trimethylsilyl)oxy]cyclohex-3-en-1-yl}oxy)silane
• CAS NO: 171734-48-8
• Molecular Weight: 300.589
• Mol File: 171734-48-8.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: tert-butyl(dimethyl)({(1S)-4-[(trimethylsilyl)oxy]cyclohex-3-en-1-yl}oxy)silane(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl(dimethyl)({(1S)-4-[(trimethylsilyl)oxy]cyclohex-3-en-1-yl}oxy)silane(171734-48-8)
• EPA Substance Registry System: tert-butyl(dimethyl)({(1S)-4-[(trimethylsilyl)oxy]cyclohex-3-en-1-yl}oxy)silane(171734-48-8)

Safety Data

• Hazardous Substances Data: 171734-48-8(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 55145-45-4 4-(tert-butyldimethylsilyloxy)cyclohexanone 
• 10416-59-8 N,O-bis-(trimethylsilyl)-acetamide 

Downstream Products

• 171867-39-3 (2S,4S)-2,4-Bis-(tert-butyl-dimethyl-silanyloxy)-cyclohexanone 
• 171734-50-2 (2R,4S)-2,4-Bis-(tert-butyl-dimethyl-silanyloxy)-cyclohexanone 
• 195607-83-1 Acetic acid (1R,5R)-5-(tert-butyl-dimethyl-silanyloxy)-2-oxo-cyclohexyl ester 
• 195607-84-2 (2R,4R)-4-(tert-Butyl-dimethyl-silanyloxy)-2-hydroxy-cyclohexanone 
• 171867-35-9 (2S,4S)-4-(tert-Butyl-dimethyl-silanyloxy)-2-hydroxy-cyclohexanone 
• 367487-78-3 [3S-(1E,3β,5α)]-[3-fluoro-5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-2-methylenecyclohexylidene]ethanol 
• 905976-90-1 (4S,6E)-4-{[tert-butyl(dimethyl)silyl]oxy}-6-(2-{[tert-butyl(diphenyl)silyl]oxy}ethylidene)cyclohex-1-en-1-yl trifluoromethanesulfonate 
• 905976-86-5 tert-butyl[((2E)-2-{(5S)-5-{[tert-butyl(dimethyl)silyl]oxy}-2-[(trimethylsilyl)methyl]cyclohex-2-en-1-ylidene}ethyl)oxy]diphenylsilane 
• 905976-89-8 1-((5S)-5-{[tert-butyl(dimethyl)silyl]oxy}-2-oxocyclohexyl)-2-{[tert-butyl(diphenyl)silyl]oxy}ethyl methanesulfonate 
• 905976-91-2 tert-butyl{[(2E)-2-((3S,5R)-5-{[tert-butyl(dimethyl)silyl]oxy}-3-fluoro-2-methylenecyclohexylidene)ethyl]oxy}diphenylsilane 
• 905976-87-6 (2E,4S)-4-{[tert-butyl(dimethyl)silyl]oxy}-2-(2-{[tert-butyl(diphenyl)silyl]oxy}ethylidene)cyclohexanone 
• 905976-88-7 (4S)-4-{[tert-butyl(dimethyl)silyl]oxy}-2-(2-{[tert-butyl(diphenyl)silyl]oxy}-1-hydroxyethyl)cyclohexanone 
• 905976-93-4 (4S)-4-{[tert-butyl(dimethyl)silyl]oxy}-2-(2-{[tert-butyl(diphenyl)silyl]oxy}-1-hydroxyethyl)cyclohexanone 
• 119478-74-9 (S)-4-((tert-butyldimethylsilyl)oxy)cyclohex-2-enone 

Relevant articles and documents

Enantioselective desymmetrization of prochiral ketones via an organocatalytic deprotonation process

The first desymmetrization of 4-substituted cyclohexanones by organocatalytic asymmetric deprotonation at low catalyst loading is reported. The combination of N,O-bis(trimethylsilyl)acetamide (BSA) and chiral quaternary ammonium aryloxide salts has been u

Towards energetically viable asymmetric deprotonations: Selectivity at more elevated temperatures with C2-symmetric magnesium bisamides

A novel chiral magnesium bisamide has enabled the development of effective asymmetric deprotonation protocols at substantially more elevated temperatures. This new, structurally simple, C2-symmetric magnesium complex displays excellent levels o

Enantioselective approaches to potential MetAP-2 reversible inhibitors

(Chemical Equation Presented) Enantioselective deprotonation of 4-substituted cyclohexanones and highly stereoselective conjugate addition of higher order mixed cuprates were the key steps in a concise synthesis of fumagalone-related molecules. The origin