171815-95-5

Basic information

• Product Name: 2-Hexanone, 3-[bis(phenylmethyl)amino]-1-chloro-5-methyl-, (3S)-
• CAS NO: 171815-95-5
• Molecular Formula: C21H26ClNO
• Molecular Weight: 343.897
• Mol File: 171815-95-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Hexanone, 3-[bis(phenylmethyl)amino]-1-chloro-5-methyl-, (3S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Hexanone, 3-[bis(phenylmethyl)amino]-1-chloro-5-methyl-, (3S)-(171815-95-5)
• EPA Substance Registry System: 2-Hexanone, 3-[bis(phenylmethyl)amino]-1-chloro-5-methyl-, (3S)-(171815-95-5)

Safety Data

• Hazardous Substances Data: 171815-95-5(Hazardous Substances Data)

Upstream product

• 100-39-0 benzyl bromide 
• 2743-60-4 L-Leucine ethyl ester 
• 593-71-5 Chloroiodomethane 
• 171815-90-0 (S)-2-Dibenzylamino-4-methyl-pentanoic acid ethyl ester 

Downstream Products

• 1383618-08-3 (1S,3S,4S)-1-cyclohexyl-4-(dibenzylamino)-6-methylheptane-1,3-diol 
• 1383618-02-7 (1R,3R,4S)-1-cyclohexyl-4-(dibenzylamino)-3-hydroxy-6-methylheptyl cyclohexanecarboxylate 
• 1383617-92-2 (1S,3S,4S)-1-cyclohexyl-4-(dibenzylamino)-3-hydroxy-6-methylheptyl cyclohexanecarboxylate 
• 1383618-07-2 (4R,6S,7S)-7-(dibenzylamino)-2,9-dimethyldecane-4,6-diol 
• 1383618-00-5 (4S,6R,7S)-7-(dibenzylamino)-6-hydroxy-2,9-dimethyldecan-4-yl 3-methylbutanoate 
• 1383617-91-1 (4R,6S,7S)-7-(dibenzylamino)-6-hydroxy-2,9-dimethyldecan-4-yl 3-methylbutanoate 
• 1383617-99-9 (4S,5R,7S)-4-(dibenzylamino)-5-hydroxy-2-methyltetradecan-7-yl octanoate 
• 1383617-90-0 (4S,5S,7R)-4-(dibenzylamino)-5-hydroxy-2-methyltetradecan-7-yl octanoate 
• 1383618-06-1 (4S,5S,7R)-4-(dibenzylamino)-2-methyltetradecane-5,7-diol 
• 171815-93-3 (2R,1'S)-2-[1-(dibenzylamino)-3-methylbutyl]oxirane 
• 341524-35-4 (-)-(2S,1'S)-1-benzyl-2-[1'-(dibenzylamino)-3'-(methyl)butyl]aziridine 
• 341524-34-3 (-)-(2S,1'S)-1-allyl-2-[1'-(dibenzylamino)-3'-(methyl)butyl]aziridine 
• 341524-24-1 (3S)-(Z)-N,N-dibenzyl-2-(benzylimino)-1-chloro-5-methylhexan-3-amine 
• 171815-92-2 (2R,3S)-3-(Dibenzylamino)-1-chloro-5-methylhexan-2-ol 

Relevant articles and documents

Highly Diastereoselective Synthesis of Threo or Erythro Aminoalkyl Epoxides from α-Amino Acids

α-Chloro-α'-(dibenzylamino)methylketones 3 are synthesized in enantiomerically pure form starting from α-amino acids.Reduction of amino ketones 3 and further epoxidation affords threo aminoalkyl epoxides 6 with diastereoisomeric excess ranging between 94percent and 98percent.The synthesis of erythro amino epoxides 9 is also described by reaction of α-amino aldehydes 7 with in situ generated (halomethyl)lithium.Amino epoxides 9 were obtained with a diastereoisomeric excess ranging between 91percent and 98percent.