171863-30-2

Basic information

• Product Name: FeCl(5,10,15-tris(pentafluorophenyl)-20-(o-(N-(((2,2'-bipyridin-6-yl-methyl)amino)acetyl)amino)phenyl)porphinate)
• CAS NO: 171863-30-2
• Molecular Weight: 1214.15
• Mol File: 171863-30-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: FeCl(5,10,15-tris(pentafluorophenyl)-20-(o-(N-(((2,2'-bipyridin-6-yl-methyl)amino)acetyl)amino)phenyl)porphinate)(CAS DataBase Reference)
• NIST Chemistry Reference: FeCl(5,10,15-tris(pentafluorophenyl)-20-(o-(N-(((2,2'-bipyridin-6-yl-methyl)amino)acetyl)amino)phenyl)porphinate)(171863-30-2)
• EPA Substance Registry System: FeCl(5,10,15-tris(pentafluorophenyl)-20-(o-(N-(((2,2'-bipyridin-6-yl-methyl)amino)acetyl)amino)phenyl)porphinate)(171863-30-2)

Safety Data

• Hazardous Substances Data: 171863-30-2(Hazardous Substances Data)

Upstream product

• 13478-10-9 iron(II) chloride tetrahydrate 

Relevant articles and documents

First Synthesis of a Binuclear [MnII(bipy)-FeIII(porphyrin)] Complex: Spectroscopic Characterization and First Evidence of Reversible Formation of Manganese(III) as Manganese Peroxidase

A [(P)FeIII-MnII] bimetallic complex, mimicking the active site of manganese peroxidase, has been synthesized. A modified highly fluorinated porphyrin, 5,10,15-tris(pentafluorophenyl)-20-(o-aminophenyl)porphyrin, has been used to introduce, through a short spacer linked to the amino function, a manganese auxiliary ligand, 6-aminomethyl-2,2′-bipyridine. Two successive metalations by FeCl2 and MnCl2 afforded the [(P)FeIII-MnII] bimetallic complex that has been characterized by elemental analysis and FAB+ mass spectrometry. X-band EPR spectroscopy and magnetic susceptibility measurements were in agreement with two high spin Fe(III) and Mn(II) centers without magnetic exchange interaction. Moreover, there is no higher intermolecular association through μ-chloro bridging as observed by EPR with a simpler chloromanganese complex, Mn(bipy)2Cl2, at high concentration. Addition of pentafluoroiodosobenzene in methanol at 0 °C led to the progressive and complete disappearance of the EPR Mn(II) signals, that were recovered after addition of a phenol. This result is consistent with Mn(III) formation. This production of Mn(III) requires the presence of the iron porphyrin and is proposed to occur through the intermediate formation of a Fe(IV) dimethoxide species which can be related to the oxidation of Mn(II) catalyzed by manganese peroxidase compound II.