172215-51-9

Basic information

• Product Name: Benzenesulfonamide, N-(1-ethenyl-1,5-dimethyl-4-hexenyl)-4-methyl-
• CAS NO: 172215-51-9
• Molecular Formula: C17H25NO2S
• Molecular Weight: 307.457
• Mol File: 172215-51-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzenesulfonamide, N-(1-ethenyl-1,5-dimethyl-4-hexenyl)-4-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfonamide, N-(1-ethenyl-1,5-dimethyl-4-hexenyl)-4-methyl-(172215-51-9)
• EPA Substance Registry System: Benzenesulfonamide, N-(1-ethenyl-1,5-dimethyl-4-hexenyl)-4-methyl-(172215-51-9)

Safety Data

• Hazardous Substances Data: 172215-51-9(Hazardous Substances Data)

Upstream product

• 31162-76-2 3,7-dimethyl-1-(phenylthio)octa-2,6-diene 
• 941-55-9 4-toluenesulfonyl azide 
• 5389-87-7 1-chloro-3,7-dimethylocta-2,6-diene 
• 20536-36-1 neryl chloride 
• 127-65-1 chloroamine-T 
• 172215-49-5 ((E)-3,7-Dimethyl-octa-2,6-dienyltellanyl)-benzene 
• 172215-50-8 ((Z)-3,7-Dimethyl-octa-2,6-dienyltellanyl)-benzene 

Relevant articles and documents

Chiral (OC)Ru(salen)-catalyzed tandem sulfimidation and [2,3]sigmatropic rearrangement: Asymmetric C-N bond formation

Asymmetric C-N bond formation was achieved in a highly enantioselective manner by using (OC)Ru(salen)-catalyzed sulfimidation and the subsequent [2,3]sigmatropic rearrangement: treatment of allyl aryl sulfides with p-toluenesulfonyl azide in the presence of a catalytic amount of (OC)Ru(salen) followed by hydrolysis of the resulting N-allyl-N-arylthio toluenesulfonamides provided N-allyl toluenesulfonamides of high enantiomeric excess.

Allylic amine formation by imination of allylic tellurides

The imination of allylic phenyl tellurides with [N-(p-toluenesulfonyl)imino]phenyliodinane or chloramine-T affords the corresponding allylic amines via [2,3]sigmatropic rearrangement of the tellurimide intermediates in high yields. Application to chiral cinnamyl 2-(1-dimethylaminoethyl)ferrocenyl telluride results in the formation of the corresponding chiral allylic amine, 3-phenyl-3-tosylaminopropene, with 93% ee.