172374-75-3

Basic information

• Product Name: μ-oxo-bis(2,3,7,8,12,13,17,18-octaethyl-5,15-dinitroporphyrinato)iron(III)
• Synonyms: μ-oxo-bis(2,3,7,8,12,13,17,18-octaethyl-5,15-dinitroporphyrinato)iron(III)
• CAS NO: 172374-75-3
• Molecular Weight: 1373.23
• Mol File: 172374-75-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: μ-oxo-bis(2,3,7,8,12,13,17,18-octaethyl-5,15-dinitroporphyrinato)iron(III)(CAS DataBase Reference)
• NIST Chemistry Reference: μ-oxo-bis(2,3,7,8,12,13,17,18-octaethyl-5,15-dinitroporphyrinato)iron(III)(172374-75-3)
• EPA Substance Registry System: μ-oxo-bis(2,3,7,8,12,13,17,18-octaethyl-5,15-dinitroporphyrinato)iron(III)(172374-75-3)

Safety Data

• Hazardous Substances Data: 172374-75-3(Hazardous Substances Data)

Upstream product

• 28755-93-3 chloro(2,3,7,8,12,13,17,18-octaethylporphyrinato-N,N',N'',N''')iron(III) complex 
• 10102-44-0 Nitrogen dioxide 

Relevant articles and documents

A μ-Oxo-bis Complex

Partial nitration of iron(III) 2,3,7,8,12,13,17,18-octaethylporphyrin chloride III(OEP)Cl>gives the μ-oxo-bis(5,15-dinitro) compound μ-oxo-bis, , which is similar to other μ-oxo-iron(III) porphyrin complexes but with less ruffling of the porphyrin structure.The porphyrin planes are not parallel and the Fe-O-Fe angle is 167.9(3) deg.As expected, the Fe atoms are significantly displaced from the porphyrin planes towards the bridging O atom: 0.46 Angstroem for Fe1 and 0.49 Angstroem for Fe2.The two porphyrin residues are eclipsed with respect to their C atoms, but the nitro groups are staggered by 90 deg from one residue to the other.