172612-21-4

Basic information

• Product Name: [In(C₆H₂(C(CH₃)3)3)(Mn(CO)5)2]
• CAS NO: 172612-21-4
• Molecular Weight: 750.228
• Mol File: 172612-21-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [In(C₆H₂(C(CH₃)3)3)(Mn(CO)5)2](CAS DataBase Reference)
• NIST Chemistry Reference: [In(C₆H₂(C(CH₃)3)3)(Mn(CO)5)2](172612-21-4)
• EPA Substance Registry System: [In(C₆H₂(C(CH₃)3)3)(Mn(CO)5)2](172612-21-4)

Safety Data

• Hazardous Substances Data: 172612-21-4(Hazardous Substances Data)

Upstream product

• 13859-41-1 sodium pentacarbonyl manganate 
• 149915-99-1 supermesityl-InBr₂ 

Relevant articles and documents

Bulky Arylgallium and Indium Derivatives with Co(CO)4 and Mn(CO)5 Substituents

Further investigation of the reaction of Ar(*)GaCl2 (Ar(*)= 2,4,6-tBu3C6H2) with Na[Mn(CO)5] resulted in the new compound, [Ga(Ar(*))(Mn(CO)5)2]2. The new indium compounds, [In(Ar(*))(Co(CO)4)2] 3 and [In(Ar(*))(Mn( CO)5)2] 4, have been prepared by the treatment of Ar(*)InBr2 with Na[Co(CO)4] and Na[Mn(CO)5], respectively. The structure of 3 was established by single-crystal X-ray diffraction: space group P1- (No.2), Z=2, a=8.625(1) A, b=10.557(2) A, c=17.55(2) A, α=88.43(1)°, β=83.45(1)°, γ=71.14(1)°. The X-ray crystal structure of[Ga(Mn(CO)5)3] is also reported: space group PBCA (No. 61), Z=8, a=12.8 3(3) A, b=11.753(2) A, c=29.662(6) A, α=β=γ=90.deegree..