1727-36-2Relevant articles and documents
Alkylations of Trichloromethylketones Effected by Trichloroacetate and a Complex Consecutive Reaction
Dehmlow, Eckehard V.,Raths, Hans-Christian
, p. 918 - 920 (2007/10/02)
A phase transfer reaction between the title ketones, sodium trichloroacetate, and an alkyl halide leads to 2a, b, 4, or 5.Whereas these compounds are fragmented by NaOH, sodium methoxide/methylmalonate/methanol give compound 8 from 5 in a complex series of consecutive rearrangements. - Key words: Trichloromethylketones, Phase Transfer Reaction