172977-38-7

Basic information

• Product Name: cis-1,3-Indandiol
• Synonyms: cis-1,3-Indandiol;(1S,3R)-Indan-1,3-diol;cis-Indan-1,3-diol
• CAS NO: 172977-38-7
• Molecular Formula: C₉H₁₀O₂
• Molecular Weight: 150.17
• Product Categories: Fused Ring Systems
• Mol File: 172977-38-7.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 337.8°C at 760 mmHg
• Flash Point: 172.8°C
• Appearance: /
• Density: 1.334g/cm³
• Vapor Pressure: 3.99E-05mmHg at 25°C
• Refractive Index: 1.661
• CAS DataBase Reference: cis-1,3-Indandiol(CAS DataBase Reference)
• NIST Chemistry Reference: cis-1,3-Indandiol(172977-38-7)
• EPA Substance Registry System: cis-1,3-Indandiol(172977-38-7)

Safety Data

• Hazardous Substances Data: 172977-38-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C9H10O2/c10-8-5-9(11)7-4-2-1-3-6(7)8/h1-4,8-11H,5H2/t8-,9-/m0/s1

Upstream product

• 606-23-5 1H-indene-1,3(2H)-dione 

Downstream Products

• 606-23-5 1H-indene-1,3(2H)-dione 

Relevant articles and documents

Chemoselective formation of cyclo-aliphatic and cyclo-olefinic 1,3-diolsviapressure hydrogenation of potentially biobased platform molecules using Kn?lker-type catalysts

The hydrogenative conversions of the biobased platform molecules 4-hydroxycyclopent-2-enone and cyclopentane-1,3-dione to their corresponding 1,3-diols are established using a pre-activated Kn?lker-type iron catalyst. The catalyst exhibits a high selectivity for ketone reduction, and does not induce dehydration. Moreover, by using different substituents of the ligand, thecis-transratio of the products can be affected substantially. A decent compatibility of this catalytic system with various structurally related substrates is demonstrated.

Facile reduction of aromatic aldehydes, ketones, diketones and oxo aldehydes to alcohols by an aqueous TiCl3/NH3 system: Selectivity and scope

A simple and rapid procedure for the almost quantitative reduction of aromatic aldehydes, ketones, diketones and oxo aldehydes to alcohols by use of TiCl3/NH3 in aqueous methanol solution is reported. The reducing system distinguishes between different classes of aldehydes and/or ketones, and many functionalities that usually do not survive under reducing conditions are tolerated well. The concept of reversal of chemoselectivity has also been developed. A mechanism based on two sequential one-electron transfers from TiIII to the carbonyl carbon atom is proposed, the second SET becoming operative only in the presence of ammonium ion (either added or formed in situ). Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002.