17314-92-0

Basic information

• Product Name: 1-Phenyl-3,3-dimethylbutane
• Synonyms: (3,3-Dimethylbutyl)benzene;1-Phenyl-3,3-dimethylbutane;3,3-Dimethylbutylbenzene
• CAS NO: 17314-92-0
• Molecular Formula: C₁₂H₁₈
• Molecular Weight: 0
• Mol File: 17314-92-0.mol
• Article Data: 25

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1-Phenyl-3,3-dimethylbutane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Phenyl-3,3-dimethylbutane(17314-92-0)
• EPA Substance Registry System: 1-Phenyl-3,3-dimethylbutane(17314-92-0)

Safety Data

• Hazardous Substances Data: 17314-92-0(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Journal of the American Chemical Society, 77, p. 1774, 1955 DOI: 10.1021/ja01612a016

Upstream product

• 2050-07-9 4-methyl-1-phenylpentan-1-one 
• 6130-96-7 1,1-dichloro-3,3-dimethylbutane 
• 96-37-7 methyl-cyclopentane 
• 71-43-2 benzene 
• 100-42-5 styrene 
• 677-22-5 tert-butylmagnesium chloride 
• 100-44-7 benzyl chloride 
• 630-19-3 pivalaldehyde 
• 507-20-0 tertiary butyl chloride 
• 90878-19-6 phenethylmagnesium chloride 
• 6721-67-1 tert-butyl benzyl ketone 
• 2259-30-5 tert-butylmagnesium bromide 
• 7065-46-5 3,3-dimethylbutanoic acid chloride 
• 1327295-66-8 tBuCH₂CH₂Au(IPr) 

Downstream Products

• 137039-61-3 1,4-dineohexyl-2,3,5,6-tetraethylbenzene 
• 137039-64-6 1,4-bis(3,3-dimethylbutyl)benzene 
• 137039-63-5 1-neohexyl-4-(tert-butylacetyl)benzene 

Relevant articles and documents

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Compound containing carbon-silicon bond and application thereof

The invention discloses a compound containing a carbon-silicon bond and application of the compound in construction of the carbon-carbon bond. The invention provides an application of a compound containing the carbon-silicon bond as shown in a formula I or a formula I' in a chemical reaction for constructing the carbon-carbon bond, wherein one carbon in the carbon-carbon bond is from carbon connected with silicon in the compound containing the carbon-silicon bond. According to the preparation method, the compound containing the carbon-silicon bond is used for providing a carbon free radical, and the carbon free radical can directly react with carbon provided in another molecule under a mild condition to construct the carbon-carbon bond; the preparation method is wider in substrate application range, is suitable for functional group activated C and carbon free radical substrates, and is also suitable for unactivated C-H bond substrates.

Catalytic Synthesis of “Super” Linear Alkenyl Arenes Using an Easily Prepared Rh(I) Catalyst

Linear alkyl benzenes (LAB) are global chemicals that are produced by acid-catalyzed reactions that involve the formation of carbocationic intermediates. One outcome of the acid-based catalysis is that 1-phenylalkanes cannot be produced. Herein, it is reported that [Rh(μ-OAc)(η2-C2H4)2]2 catalyzes production of 1-phenyl substituted alkene products via oxidative arene vinylation. Since C C bonds can be used for many chemical transformations, the formation of unsaturated products provides a potential advantage over current processes that produce saturated alkyl arenes. Conditions that provide up to a 10:1 linear:branched ratio have been achieved, and catalytic turnovers >1470 have been demonstrated. In addition, electron-deficient and electron-rich substituted benzenes are successfully alkylated. The Rh catalysis provides ortho:meta:para selectivity that is opposite to traditional acid-based catalysis.