173602-45-4

Basic information

• Product Name: methyl (Z)-10-cyano-9-decenoate
• Synonyms: methyl (Z)-10-cyano-9-decenoate
• CAS NO: 173602-45-4
• Molecular Weight: 209.288
• Mol File: 173602-45-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: methyl (Z)-10-cyano-9-decenoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (Z)-10-cyano-9-decenoate(173602-45-4)
• EPA Substance Registry System: methyl (Z)-10-cyano-9-decenoate(173602-45-4)

Safety Data

• Hazardous Substances Data: 173602-45-4(Hazardous Substances Data)

Upstream product

• 112-62-9 Methyl oleate 
• 107-13-1 acrylonitrile 
• 13481-97-5 dimethyl (Z)-octadec-9-ene-1,18-dioate 
• 13481-97-5 dimethyl 9-octadecen-1,18-dioate 

Relevant articles and documents

Ruthenium-alkylidene catalysed cross-metathesis of fatty acid derivatives with acrylonitrile and methyl acrylate: A key step toward long-chain bifunctional and amino acid compounds

The ruthenium catalysed cross-metathesis of fatty-esters arising from plant oils with acrylonitrile is presented. The resulting linear nitrile ester products have potential as new intermediates for polyamides synthesis. A series of commercially available catalysts are able to promote the transformation of methyl 10-undecenoate 1, dimethyl octadec-9-en-1,18-dioate 5 and methyl ricinoleate 9 with acrylonitrile and a protocol based on the slow addition of catalyst allowed TONs as high as 1900 (92% yield) to be reached for cross-metathesis with acrylonitrile. These cross-metathesis conditions have been applied to methyl acrylate and TONs up to 7600 were obtained.

CROSS METATHESIS APPROACH TO C11-C13 FATTY-CHAIN AMINO ESTERS FORM OLEIC ACID DERIVATIVES

A concise method of producing nylon 11, 12, or 13 precursors from oleic acid or an ester of oleic acid is described. The method involves cross-metathesis reactions as the key C-C bond formation step. Subsequent steps are provided to convert the metathesis product to the corresponding nylon precursors. Also provided are the products of the method.