174172-99-7Relevant articles and documents
Direct synthesis of diastereomerically pure glycosyl sulfonium salts
Mydock, Laurel K.,Kamat, Medha N.,Demchenko, Alexei V.
supporting information; scheme or table, p. 2928 - 2931 (2011/07/30)
It is reported that stable glycosyl sulfonium salts can be generated via direct anomeric S-methylation of ethylthioglycosides. Mechanistically, this pathway represents the first step in the activation of thioglycosides for glycosidation; however, it can f
PARTIAL SUBSTITUTION OF THIOGLYCOSIDES BY PHASE TRANSFER CATALYZED BENZOYLATION AND BENZYLATION
Garegg, Per J.,Kvarnstroem, Ingemar,Niklasson, Annika,Niklasson, Gunilla,Svensson, Stefan C. T.
, p. 933 - 954 (2007/10/02)
Partial substitution by phase transfer catalysis giving monobenzoylated and monobenzylated products from 2,3- and from 4,6-diols in ethyl 1-thio-D-hexopyranosides with the β-gluco, β-galacto- and α-manno-configurations are described.Two disaccharide thiog