17425-91-1

Basic information

• Product Name: Silanamine, 1,1,1-trimethyl-N,N-diphenyl-
• Synonyms: Silanamine, 1,1,1-trimethyl-N,N-diphenyl-
• CAS NO: 17425-91-1
• Molecular Formula: C₁₅H₁₉NSi
• Molecular Weight: 0
• Mol File: 17425-91-1.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 298.5°Cat760mmHg
• Flash Point: 134.3°C
• Appearance: /
• Density: 0.994g/cm³
• Vapor Pressure: 0.00126mmHg at 25°C
• Refractive Index: 1.558
• CAS DataBase Reference: Silanamine, 1,1,1-trimethyl-N,N-diphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silanamine, 1,1,1-trimethyl-N,N-diphenyl-(17425-91-1)
• EPA Substance Registry System: Silanamine, 1,1,1-trimethyl-N,N-diphenyl-(17425-91-1)

Safety Data

• Hazardous Substances Data: 17425-91-1(Hazardous Substances Data)

Usage

InChI:InChI=1/C15H19NSi/c1-17(2,3)16(14-10-6-4-7-11-14)15-12-8-5-9-13-15/h4-13H,1-3H3

Upstream product

• 25436-07-1 trimethylsilyl trichloroacetate 
• 122-39-4 diphenylamine 
• 75-77-4 chloro-trimethyl-silane 
• 122-66-7 diphenyl hydrazine 
• 591-50-4 iodobenzene 
• 3768-55-6 N-trimethylsilylaniline 
• 5856-89-3 lithium diphenylamide 
• 1206-46-8 trimethyl(pentafluorophenyl)silane 

Downstream Products

• 122-39-4 diphenylamine 
• 1159100-85-2 9,9-dioctyl-N,N,N’,N’-tetraphenyl-9H-fluorene-2,7-diamine 
• 1262758-37-1 7-bromo-9,9-dioctyl-N,N-diphenyl-9H-fluoren-2-amine 
• 4316-53-4 diphenyl(p-tolyl)amine 
• 4316-50-1 N,N-dimethyl-N',N'-diphenyl-1,4-phenylenediamine 
• 4316-51-2 N,N-diphenyl-4-methoxyaniline 
• 603-34-9 N,N-diphenylaminobenzene 
• 6940-30-3 2-(N,N-diphenylamino)naphthalene 
• 61231-45-6 1-(N,N-diphenylamino)naphthalene 
• 4316-55-6 2-methyl-N,N-diphenylaniline 
• 36809-32-2 N-(4-trifluoromethylphenyl)-N-methylaniline 
• 16911-33-4 (4-(N,N-diphenylamino)phenyl)(phenyl)methanone 
• 14118-16-2 N,N,N',N'-tetraphenyl-p-phenylenediamine 
• 180049-26-7 dibromo[tris(diphenylamido)]niobium(V) tetrahydrofuran solvate 

Relevant articles and documents

Structural chemistry of alkali metal phenylhydrazides

The crystal and molecular structures of a series of N-phenylsubstituted lithium hydrazides were determined in order to investigate possible Li...Ph π interactions. These are pronounced when there are no donor molecules present to solvate the Li centers. A

Palladium catalysed aryl amination reactions in supercritical carbon dioxide

Palladium catalysed C-N bond formation in supercritical carbon dioxide has been accomplished. Carbamic acid formation is avoided in part through the use of an N-silylamine as the coupling partner. Employing a catalyst system of Pd 2dba3 (1 mol%) and 2-dicyclohexylphosphino-2′, 4′,6′-triisopropyl-1,1′-biphenyl (X-Phos) (2 mol%) enabled the catalytic amination of aryl bromides and chlorides with N-silylanilines to be realised in excellent yield. Extension of the methodology to the N-arylation of N-silyldiarylamines, N-silylazoles and N-silylsulfonamides is reported. The Royal Society of Chemistry 2005.

NOVEL TRICHLOROACETYL BASED SILYLATIONS: SIMPLE METHODS FOR t-BUTYLDIMETHYLSILYLATIONS AND FOR THE PROTECTION OF AMINO GROUPS.

A new reagent for t-butyldimethylsilylation has been developed and the known trimethylsilyl trichloroacetate (1) has been shown to be of use for N-silylating amines.