174735-88-7

Basic information

• Product Name: ((C₆F₅NC₂H₄)3N)TiI
• Synonyms: ((C₆F₅NC₂H₄)3N)TiI
• CAS NO: 174735-88-7
• Molecular Weight: 816.147
• Mol File: 174735-88-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ((C₆F₅NC₂H₄)3N)TiI(CAS DataBase Reference)
• NIST Chemistry Reference: ((C₆F₅NC₂H₄)3N)TiI(174735-88-7)
• EPA Substance Registry System: ((C₆F₅NC₂H₄)3N)TiI(174735-88-7)

Safety Data

• Hazardous Substances Data: 174735-88-7(Hazardous Substances Data)

Upstream product

• 7720-83-4 titanium(IV) iodide 
• 155019-77-5 2,2',2''-tris<(pentafluorophenyl)amino>triethylamine 

Downstream Products

• 174735-90-1 ((C₆F₅NC₂H₄)3N)Ti(CH₃) 

Relevant articles and documents

Synthesis of titanium complexes that contain triamido-amine ligands

We report the synthesis of a variety of titanium complexes that contain (Et3SiNCH2CH2)3N, (C6F5NCH2CH2)3N, or (Me3SiNCH2CH2CH2)3N ligands. Complexes in the first category include [(Et3SiNCH2CH2)3N]TiCl, [(Et3SiNCH2CH2)3N]Ti(OTf), and [(Et3SiNCH2CH2)3N]Ti-(t-Bu). Complexes in the second category include [(C6F5NCH2CH2)3N]TiX (X = Cl, Br, I, OTf) and [(C6F5NCH2CH2)3N]TiR (R = Me, Et). Complexes in the third category include [(Me3SiNCH2CH2CH2)3N]TiCl and [(Me3SiNCH2CH2CH2) 3N]TiCH3. In an X-ray study [(Me3-SiNCH2CH2CH2) 3N]TiCl was shown to contain a coordinated amino nitrogen and TiN2C3 rings that were puckered in a pseudocyclohexane chair form. The TiN2C3 rings are proposed to "flip" via dissociation of the amino nitrogen donor in the methyl complex, but the flipping rate is slow on the NMR time scale in [(Me3SiNCH2CH2CH2)3N]TiCl as a consequence of the greater electrophilicity of the metal.