174904-18-8

Basic information

• Product Name: [CpFe(dppe)(η(1)-CNCH3)]PF6
• Synonyms: [CpFe(dppe)(η(1)-CNCH3)]PF6
• CAS NO: 174904-18-8
• Molecular Weight: 705.382
• Mol File: 174904-18-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: [CpFe(dppe)(η(1)-CNCH3)]PF6(CAS DataBase Reference)
• NIST Chemistry Reference: [CpFe(dppe)(η(1)-CNCH3)]PF6(174904-18-8)
• EPA Substance Registry System: [CpFe(dppe)(η(1)-CNCH3)]PF6(174904-18-8)

Safety Data

• Hazardous Substances Data: 174904-18-8(Hazardous Substances Data)

Upstream product

• 17084-13-8 potassium hexafluorophosphate 
• 70460-15-0 [CpFe(dppe)(CN)] 
• 74-88-4 methyl iodide 
• 38834-26-3 (η5-Cp)Fe(CO)3PF6 
• 75-05-8 acetonitrile 
• 1663-45-2 1,2-bis-(diphenylphosphino)ethane 

Relevant articles and documents

Donor-acceptor properties of the methyl cyanide and methyl isocyanide ligands towards the fragment CpFe(dppe)

The complexes [CpFe(dppe)NCCH3]PF6 and [CpFe(dppe)CNCH3]PF6, Cp = η5-C5H5, dppe = Ph2P(CH2)2PPh2, have been prepared and characterized

BIS- AND TRIS-ACETONITRILE COMPLEXES OF IRON(II)

Photolysis of +PF6- in CH3CN in the presence of 2-, 4- or 6-electron ligands gives +PF6- (n=1:L=CO, PPh3, cyclohexene, dimethylthiophene; n=2:L2=dppe or n=3:L3=cyclooctatetraene, or three phospholes), whereas in the absence of added ligand a thermally stable purple tris(acetonitrile) complex is isolable only using permethylated Cp.The synthetic potential of the acetonitrile complexes is illustrated by the stepwise replacement of the acetonitrile ligands.